Unstable intermediates. Part XXXVII. The electron spin resonance spectra of nitro-radical anions in fluid and rigid media
Тип публикации: Journal Article
Дата публикации: 1966-01-01
SJR: —
CiteScore: —
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ISSN: 00224944
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
The anions of various mono- and di-nitro aromatic compounds and their conjugate acids have been studied by electron spin resonance at room temperature and 77°K. The anisotropic hyperfine coupling constants to 14N deduced from the solid-state spectra have been used to estimate the spin-density on nitrogen. A marked decrease in the ratio of the anisotropic to the isotropic coupling as the spin-density increases has been interpreted in terms of a slight tendency for the nitro-group to become pyramidal.
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Fox W. M., Gross J. M., Symons M. C. R. Unstable intermediates. Part XXXVII. The electron spin resonance spectra of nitro-radical anions in fluid and rigid media // Journal of the Chemical Society A Inorganic Physical Theoretical. 1966. p. 448.
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Fox W. M., Gross J. M., Symons M. C. R. Unstable intermediates. Part XXXVII. The electron spin resonance spectra of nitro-radical anions in fluid and rigid media // Journal of the Chemical Society A Inorganic Physical Theoretical. 1966. p. 448.
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TY - JOUR
DO - 10.1039/j19660000448
UR - https://doi.org/10.1039/j19660000448
TI - Unstable intermediates. Part XXXVII. The electron spin resonance spectra of nitro-radical anions in fluid and rigid media
T2 - Journal of the Chemical Society A Inorganic Physical Theoretical
AU - Fox, W M
AU - Gross, J M
AU - Symons, M. C. R.
PY - 1966
DA - 1966/01/01
PB - Royal Society of Chemistry (RSC)
SP - 448
SN - 0022-4944
ER -
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@article{1966_Fox,
author = {W M Fox and J M Gross and M. C. R. Symons},
title = {Unstable intermediates. Part XXXVII. The electron spin resonance spectra of nitro-radical anions in fluid and rigid media},
journal = {Journal of the Chemical Society A Inorganic Physical Theoretical},
year = {1966},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/j19660000448},
pages = {448},
doi = {10.1039/j19660000448}
}
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