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страницы 2630-2633
Synthesis, structure, and properties of π-cyclo-octenyl-π-cyclo-octa-1,5-dienecobalt
Тип публикации: Journal Article
Дата публикации: 1968-01-01
SJR: —
CiteScore: —
Impact factor: —
ISSN: 00224944
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
Treatment of cobalt dichloride suspended in a mixture of cyclo-octa-1,5-diene, pyridine, and tetrahydrofuran with metal sodium affords a brown crystalline complex, Co(C8H13)(C8H12). Structural proof has been obtained which shows conclusively that the complex is π-cyclo-octenyl-π-cyclo-octa-1,5-dienecobalt. Thermally it is stable, and shows no tendency for valence tautomerism. Remarkable mobility of the hydrogen atoms of the ligand has been observed in some chemical reactions, and this is interpreted in terms of the molecular structure.
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Otsuka S., Rossi M. Synthesis, structure, and properties of π-cyclo-octenyl-π-cyclo-octa-1,5-dienecobalt // Journal of the Chemical Society A Inorganic Physical Theoretical. 1968. pp. 2630-2633.
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Otsuka S., Rossi M. Synthesis, structure, and properties of π-cyclo-octenyl-π-cyclo-octa-1,5-dienecobalt // Journal of the Chemical Society A Inorganic Physical Theoretical. 1968. pp. 2630-2633.
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TY - JOUR
DO - 10.1039/j19680002630
UR - https://doi.org/10.1039/j19680002630
TI - Synthesis, structure, and properties of π-cyclo-octenyl-π-cyclo-octa-1,5-dienecobalt
T2 - Journal of the Chemical Society A Inorganic Physical Theoretical
AU - Otsuka, S.
AU - Rossi, M
PY - 1968
DA - 1968/01/01
PB - Royal Society of Chemistry (RSC)
SP - 2630-2633
SN - 0022-4944
ER -
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BibTex (до 50 авторов)
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@article{1968_Otsuka,
author = {S. Otsuka and M Rossi},
title = {Synthesis, structure, and properties of π-cyclo-octenyl-π-cyclo-octa-1,5-dienecobalt},
journal = {Journal of the Chemical Society A Inorganic Physical Theoretical},
year = {1968},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/j19680002630},
pages = {2630--2633},
doi = {10.1039/j19680002630}
}
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