Synlett, volume 34, issue 11, pages 1247-1252
Catalyst-Free Oxidation of Sulfides to Sulfoxides by gem-Dihydroperoxide under Mild Conditions
Nadezhda M Andriyashina
1
,
Arkadiy V Antipin
1
,
Rustam L. Safiullin
1
Publication type: Journal Article
Publication date: 2023-01-18
Organic Chemistry
Abstract
A facile and efficient method for the oxidation of sulfides (dialkyl, phenylalkyl, benzylalkyl) to sulfoxides under mild conditions without using any catalysts is reported. This method afforded a series of sulfoxides with good yields (>95%). The ready accessibility and low cost of the gem-dihydroperoxides will endow it with attractive applications in chemical synthesis as oxidants.
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