Boron Trifluoride as an Efficient Catalyst for the Selective Synthesis of Tricyclic Monoperoxides from β,δ-Triketones and H2O2
Publication type: Journal Article
Publication date: 2012-12-06
scimago Q2
wos Q2
SJR: 0.559
CiteScore: 4.6
Impact factor: 2.3
ISSN: 00397881, 1437210X
Catalysis
Organic Chemistry
Abstract
Boron trifluoride was found to serve as an efficient catalyst for the reaction of β,δ-triketones with H 2 O 2 producing tricyclic monoperoxides in yields from 48–93%. BF 3 acts simultaneously as a catalyst and co-solvent. The synthesis can be scaled up to tens of grams. The resulting peroxides can be easily isolated from the reaction mixture by column chromatography.
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Total citations:
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Citations from 2024:
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(3%)
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GOST
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Terent'ev A. O. et al. Boron Trifluoride as an Efficient Catalyst for the Selective Synthesis of Tricyclic Monoperoxides from β,δ-Triketones and H2O2 // Synthesis. 2012. Vol. 45. No. 02. pp. 246-250.
GOST all authors (up to 50)
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Terent'ev A. O., Yaremenko I. A., Vil V., Dembitsky V., Nikishin G. Boron Trifluoride as an Efficient Catalyst for the Selective Synthesis of Tricyclic Monoperoxides from β,δ-Triketones and H2O2 // Synthesis. 2012. Vol. 45. No. 02. pp. 246-250.
Cite this
RIS
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TY - JOUR
DO - 10.1055/s-0032-1317895
UR - https://doi.org/10.1055/s-0032-1317895
TI - Boron Trifluoride as an Efficient Catalyst for the Selective Synthesis of Tricyclic Monoperoxides from β,δ-Triketones and H2O2
T2 - Synthesis
AU - Terent'ev, Alexander O.
AU - Yaremenko, Ivan A
AU - Vil, Vera
AU - Dembitsky, Valery
AU - Nikishin, Gennady
PY - 2012
DA - 2012/12/06
PB - Georg Thieme Verlag KG
SP - 246-250
IS - 02
VL - 45
SN - 0039-7881
SN - 1437-210X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2012_Terent'ev,
author = {Alexander O. Terent'ev and Ivan A Yaremenko and Vera Vil and Valery Dembitsky and Gennady Nikishin},
title = {Boron Trifluoride as an Efficient Catalyst for the Selective Synthesis of Tricyclic Monoperoxides from β,δ-Triketones and H2O2},
journal = {Synthesis},
year = {2012},
volume = {45},
publisher = {Georg Thieme Verlag KG},
month = {dec},
url = {https://doi.org/10.1055/s-0032-1317895},
number = {02},
pages = {246--250},
doi = {10.1055/s-0032-1317895}
}
Cite this
MLA
Copy
Terent'ev, Alexander O., et al. “Boron Trifluoride as an Efficient Catalyst for the Selective Synthesis of Tricyclic Monoperoxides from β,δ-Triketones and H2O2.” Synthesis, vol. 45, no. 02, Dec. 2012, pp. 246-250. https://doi.org/10.1055/s-0032-1317895.