Synlett, volume 27, issue 09, pages 1367-1370
GaCl3-Mediated Isomerization of Donor–Acceptor Cyclopropanes into (2-Arylalkylidene)malonates
Publication type: Journal Article
Publication date: 2016-03-01
Organic Chemistry
Abstract
A new process for isomerization of donor–acceptor cyclopropanes (2-arylcyclopropanedicarboxylates) by treatment with anhydrous gallium trichloride to give (2-arylalkylidene)malonates in high yields and with good selectivity has been developed. The reaction involves initial formation of a 1,2-dipolar gallium complex.
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Novikov R. G., Tarasova A., Tomilov Y. V. GaCl3-Mediated Isomerization of Donor–Acceptor Cyclopropanes into (2-Arylalkylidene)malonates // Synlett. 2016. Vol. 27. No. 09. pp. 1367-1370.
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Novikov R. G., Tarasova A., Tomilov Y. V. GaCl3-Mediated Isomerization of Donor–Acceptor Cyclopropanes into (2-Arylalkylidene)malonates // Synlett. 2016. Vol. 27. No. 09. pp. 1367-1370.
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TY - JOUR
DO - 10.1055/s-0035-1561389
UR - https://doi.org/10.1055/s-0035-1561389
TI - GaCl3-Mediated Isomerization of Donor–Acceptor Cyclopropanes into (2-Arylalkylidene)malonates
T2 - Synlett
AU - Novikov, Roman G.
AU - Tarasova, Anna
AU - Tomilov, Yury V.
PY - 2016
DA - 2016/03/01
PB - Georg Thieme Verlag KG
SP - 1367-1370
IS - 09
VL - 27
SN - 0936-5214
SN - 1437-2096
ER -
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BibTex (up to 50 authors)
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@article{2016_Novikov,
author = {Roman G. Novikov and Anna Tarasova and Yury V. Tomilov},
title = {GaCl3-Mediated Isomerization of Donor–Acceptor Cyclopropanes into (2-Arylalkylidene)malonates},
journal = {Synlett},
year = {2016},
volume = {27},
publisher = {Georg Thieme Verlag KG},
month = {mar},
url = {https://doi.org/10.1055/s-0035-1561389},
number = {09},
pages = {1367--1370},
doi = {10.1055/s-0035-1561389}
}
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MLA
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Novikov, Roman G., et al. “GaCl3-Mediated Isomerization of Donor–Acceptor Cyclopropanes into (2-Arylalkylidene)malonates.” Synlett, vol. 27, no. 09, Mar. 2016, pp. 1367-1370. https://doi.org/10.1055/s-0035-1561389.
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