volume 28 issue 18 pages 2489-2494

Thieme Chemistry Journals Awardees – Where Are They Now? Titanium-Catalyzed Hydroaminoalkylation of Vinylsilanes and a One-Pot Procedure for the Synthesis of 1,4-Benzoazasilines

Publication typeJournal Article
Publication date2017-07-18
scimago Q3
wos Q3
SJR0.437
CiteScore3.3
Impact factor1.4
ISSN09365214, 14372096
Organic Chemistry
Abstract

Vinylsilanes undergo intermolecular alkene hydroaminoalkylation with secondary amines in the presence of a titanium mono(aminopyridinato) catalyst to give the branched hydroaminoalkylation products with high regioselectivity. Corresponding reactions of a suitable (2-bromophenyl)vinylsilane combined with a subsequent intramolecular Buchwald–Hartwig amination result in the development of an elegant one-pot procedure for the synthesis of 1,4-benzoazasilines.

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Doye S., Rosien M., Doye S. Thieme Chemistry Journals Awardees – Where Are They Now? Titanium-Catalyzed Hydroaminoalkylation of Vinylsilanes and a One-Pot Procedure for the Synthesis of 1,4-Benzoazasilines // Synlett. 2017. Vol. 28. No. 18. pp. 2489-2494.
GOST all authors (up to 50) Copy
Doye S., Rosien M., Doye S. Thieme Chemistry Journals Awardees – Where Are They Now? Titanium-Catalyzed Hydroaminoalkylation of Vinylsilanes and a One-Pot Procedure for the Synthesis of 1,4-Benzoazasilines // Synlett. 2017. Vol. 28. No. 18. pp. 2489-2494.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1055/s-0036-1589048
UR - https://doi.org/10.1055/s-0036-1589048
TI - Thieme Chemistry Journals Awardees – Where Are They Now? Titanium-Catalyzed Hydroaminoalkylation of Vinylsilanes and a One-Pot Procedure for the Synthesis of 1,4-Benzoazasilines
T2 - Synlett
AU - Doye, Sven
AU - Rosien, Michael
AU - Doye, Sven
PY - 2017
DA - 2017/07/18
PB - Georg Thieme Verlag KG
SP - 2489-2494
IS - 18
VL - 28
SN - 0936-5214
SN - 1437-2096
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2017_Doye,
author = {Sven Doye and Michael Rosien and Sven Doye},
title = {Thieme Chemistry Journals Awardees – Where Are They Now? Titanium-Catalyzed Hydroaminoalkylation of Vinylsilanes and a One-Pot Procedure for the Synthesis of 1,4-Benzoazasilines},
journal = {Synlett},
year = {2017},
volume = {28},
publisher = {Georg Thieme Verlag KG},
month = {jul},
url = {https://doi.org/10.1055/s-0036-1589048},
number = {18},
pages = {2489--2494},
doi = {10.1055/s-0036-1589048}
}
MLA
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MLA Copy
Doye, Sven, et al. “Thieme Chemistry Journals Awardees – Where Are They Now? Titanium-Catalyzed Hydroaminoalkylation of Vinylsilanes and a One-Pot Procedure for the Synthesis of 1,4-Benzoazasilines.” Synlett, vol. 28, no. 18, Jul. 2017, pp. 2489-2494. https://doi.org/10.1055/s-0036-1589048.