Synthesis, volume 50, issue 01, pages 49-63
Turning the Light On: Recent Developments in Photoinduced Olefin Metathesis
N Gabriel Lemcoff
1, 2
,
Or Eivgi
1
Publication type: Journal Article
Publication date: 2017-09-21
Catalysis
Organic Chemistry
Abstract
Olefin metathesis is one of the most important methods to form carbon–carbon double bonds and has found many applications in industry and academia. The ability to initiate the reaction using external stimulus such as light, with high spatial and temporal resolution is highly advantageous and provides creative novel opportunities in organic syntheses and material sciences. This review article covers recent advances in light-activated olefin metathesis reactions from the development of novel complexes that can be initiated photochemically to recently reported applications of photoinduced olefin metathesis, as well as the bright newly emerging field of photoredox-mediated metal-free ROMP.
1 Introduction
2 Light-Activated Olefin Metathesis Complexes
2.1 Sulfur-Chelated Hoveyda–Grubbs-Type Complexes
2.2 Nitrogen-Chelated Hoveyda–Grubbs-Type Complexes
2.3 Catalyst Activation with Photoacid Generators
2.4 Phototuning of Active Complexes
2.5 Photoactivation of Non-Grubbs-Type Olefin Metathesis Complexes
3 Photoredox-Mediated Metal-Free ROMP
4 Applications of Photoinduced Olefin Metathesis
4.1 Chromatic Orthogonal Olefin Metathesis
4.2 UV-Filter-Assisted Olefin Metathesis
4.3 Photolithographic Olefin Metathesis Polymerization
5 Conclusions
Top-30
Citations by journals
|
1
2
3
4
5
6
7
|
|
|
ACS Catalysis
7 publications, 15.91%
|
|
|
Journal of the American Chemical Society
3 publications, 6.82%
|
|
|
Molecules
2 publications, 4.55%
|
|
|
Macromolecules
2 publications, 4.55%
|
|
|
Organometallics
2 publications, 4.55%
|
|
|
Chemistry - A European Journal
2 publications, 4.55%
|
|
|
Angewandte Chemie
2 publications, 4.55%
|
|
|
Angewandte Chemie - International Edition
2 publications, 4.55%
|
|
|
Chemical Science
2 publications, 4.55%
|
|
|
Nature Chemistry
1 publication, 2.27%
|
|
|
Nature Reviews Chemistry
1 publication, 2.27%
|
|
|
Journal of Coordination Chemistry
1 publication, 2.27%
|
|
|
Coordination Chemistry Reviews
1 publication, 2.27%
|
|
|
Polymer
1 publication, 2.27%
|
|
|
Progress in Organic Coatings
1 publication, 2.27%
|
|
|
Journal of Organometallic Chemistry
1 publication, 2.27%
|
|
|
European Journal of Organic Chemistry
1 publication, 2.27%
|
|
|
ACS Omega
1 publication, 2.27%
|
|
|
Inorganic Chemistry
1 publication, 2.27%
|
|
|
ACS Applied Polymer Materials
1 publication, 2.27%
|
|
|
ACS Macro Letters
1 publication, 2.27%
|
|
|
Accounts of Chemical Research
1 publication, 2.27%
|
|
|
Chemistry of Materials
1 publication, 2.27%
|
|
|
RSC Advances
1 publication, 2.27%
|
|
|
Organic and Biomolecular Chemistry
1 publication, 2.27%
|
|
|
Polymer Chemistry
1 publication, 2.27%
|
|
|
Catalysis Science and Technology
1 publication, 2.27%
|
|
|
Russian Chemical Reviews
1 publication, 2.27%
|
|
|
1
2
3
4
5
6
7
|
Citations by publishers
|
5
10
15
20
|
|
|
American Chemical Society (ACS)
20 publications, 45.45%
|
|
|
Wiley
8 publications, 18.18%
|
|
|
Royal Society of Chemistry (RSC)
6 publications, 13.64%
|
|
|
Elsevier
4 publications, 9.09%
|
|
|
Springer Nature
2 publications, 4.55%
|
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
2 publications, 4.55%
|
|
|
Taylor & Francis
1 publication, 2.27%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 2.27%
|
|
|
5
10
15
20
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2017,2018,2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0,0],"imageUrls":["","","","","","","",""],"datasets":[{"label":"Citations number","data":[1,8,7,13,7,3,4,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["2.27","18.18","15.91","29.55","15.91","6.82","9.09","2.27"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["ACS Catalysis","Journal of the American Chemical Society","Molecules","Macromolecules","Organometallics","Chemistry - A European Journal","Angewandte Chemie","Angewandte Chemie - International Edition","Chemical Science","Nature Chemistry","Nature Reviews Chemistry","Journal of Coordination Chemistry","Coordination Chemistry Reviews","Polymer","Progress in Organic Coatings","Journal of Organometallic Chemistry","European Journal of Organic Chemistry","ACS Omega","Inorganic Chemistry","ACS Applied Polymer Materials","ACS Macro Letters","Accounts of Chemical Research","Chemistry of Materials","RSC Advances","Organic and Biomolecular Chemistry","Polymer Chemistry","Catalysis Science and Technology","Russian Chemical Reviews"],"ids":[4873,4813,1770,20817,1409,24708,25450,19215,9646,17228,6657,23053,13437,19955,17883,11834,19472,18901,24714,25373,957,1526,6428,3100,541,11501,2605,23802],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/5YZtvLvkPZuc2JHOaZsjCvGSHFCuC3drUwN3YAc5_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[7,3,2,2,2,2,2,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[15.91,6.82,4.55,4.55,4.55,4.55,4.55,4.55,4.55,2.27,2.27,2.27,2.27,2.27,2.27,2.27,2.27,2.27,2.27,2.27,2.27,2.27,2.27,2.27,2.27,2.27,2.27,2.27],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["American Chemical Society (ACS)","Wiley","Royal Society of Chemistry (RSC)","Elsevier","Springer Nature","Multidisciplinary Digital Publishing Institute (MDPI)","Taylor & Francis","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[40,11,123,17,8,202,18,9422],"codes":[0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/5YZtvLvkPZuc2JHOaZsjCvGSHFCuC3drUwN3YAc5_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[20,8,6,4,2,2,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[45.45,18.18,13.64,9.09,4.55,4.55,2.27,2.27],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,0,0,0,0],"percentage":["0","0","0","0","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,2,0,0,0,0,0,0],"percentage":["0","4.55","0","0","0","0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,0,1,1,0,1,0,0],"percentage":["0","0","2.27","2.27","0","2.27","0","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[1,6,6,12,7,1,4,1],"percentage":["2.27","13.64","13.64","27.27","15.91","2.27","9.09","2.27"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,0,0,0,0,1,0,0],"percentage":["0","0","0","0","0","2.27","0","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,0,0,0,0],"percentage":["0","0","0","0","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,1,0,0,0,0,0,0],"percentage":["0","2.27","0","0","0","0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[1,3,1,4,1,1,1,0],"percentage":["2.27","6.82","2.27","9.09","2.27","2.27","2.27","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[0,4,6,8,5,1,3,1],"percentage":["0","9.09","13.64","18.18","11.36","2.27","6.82","2.27"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,0,0,1,1,1,0,0],"percentage":["0","0","0","2.27","2.27","2.27","0","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Lemcoff N. G., Eivgi O. Turning the Light On: Recent Developments in Photoinduced Olefin Metathesis // Synthesis. 2017. Vol. 50. No. 01. pp. 49-63.
GOST all authors (up to 50)
Copy
Lemcoff N. G., Eivgi O. Turning the Light On: Recent Developments in Photoinduced Olefin Metathesis // Synthesis. 2017. Vol. 50. No. 01. pp. 49-63.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1055/s-0036-1589113
UR - https://doi.org/10.1055/s-0036-1589113
TI - Turning the Light On: Recent Developments in Photoinduced Olefin Metathesis
T2 - Synthesis
AU - Lemcoff, N Gabriel
AU - Eivgi, Or
PY - 2017
DA - 2017/09/21 00:00:00
PB - Thieme
SP - 49-63
IS - 01
VL - 50
SN - 0039-7881
SN - 1437-210X
ER -
Cite this
BibTex
Copy
@article{2017_Lemcoff,
author = {N Gabriel Lemcoff and Or Eivgi},
title = {Turning the Light On: Recent Developments in Photoinduced Olefin Metathesis},
journal = {Synthesis},
year = {2017},
volume = {50},
publisher = {Thieme},
month = {sep},
url = {https://doi.org/10.1055/s-0036-1589113},
number = {01},
pages = {49--63},
doi = {10.1055/s-0036-1589113}
}
Cite this
MLA
Copy
Lemcoff, N. Gabriel, et al. “Turning the Light On: Recent Developments in Photoinduced Olefin Metathesis.” Synthesis, vol. 50, no. 01, Sep. 2017, pp. 49-63. https://doi.org/10.1055/s-0036-1589113.
Profiles