volume 50 issue 09 pages 1737-1749

Cu-Catalyzed Borylative and Silylative Transformations of Allenes: Use of β-Functionalized Allyl Copper Intermediates in Organic Synthesis

Publication typeJournal Article
Publication date2018-03-20
scimago Q2
wos Q2
SJR0.559
CiteScore4.6
Impact factor2.3
ISSN00397881, 1437210X
Catalysis
Organic Chemistry
Abstract

Herein, copper-catalyzed borylative and silylative transformations of allenes using borylcopper or silylcopper as the active catalytic species are described. First, the synthesis and characterization of borylcopper and silylcopper complexes are briefly introduced. Next, the borylative transformations of allenes are summarized including hydro­boration, carboboration, and borylative allylation of carbonyl compounds. We next deal with the silylative transformations of allenes such as hydrosilylation, carbosilylation, and silylative allylation of carbonyl compounds.

1 Introduction

2 Synthesis of Borylcopper and Silylcopper Complexes

3 Borylative Transformations

4 Silylative Transformations

5 Conclusions and Future Outlook

Found 
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Fujihara T., Tsuji Y. Cu-Catalyzed Borylative and Silylative Transformations of Allenes: Use of β-Functionalized Allyl Copper Intermediates in Organic Synthesis // Synthesis. 2018. Vol. 50. No. 09. pp. 1737-1749.
GOST all authors (up to 50) Copy
Fujihara T., Tsuji Y. Cu-Catalyzed Borylative and Silylative Transformations of Allenes: Use of β-Functionalized Allyl Copper Intermediates in Organic Synthesis // Synthesis. 2018. Vol. 50. No. 09. pp. 1737-1749.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1055/s-0036-1591777
UR - https://doi.org/10.1055/s-0036-1591777
TI - Cu-Catalyzed Borylative and Silylative Transformations of Allenes: Use of β-Functionalized Allyl Copper Intermediates in Organic Synthesis
T2 - Synthesis
AU - Fujihara, Tetsuaki
AU - Tsuji, Yasushi
PY - 2018
DA - 2018/03/20
PB - Georg Thieme Verlag KG
SP - 1737-1749
IS - 09
VL - 50
SN - 0039-7881
SN - 1437-210X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Fujihara,
author = {Tetsuaki Fujihara and Yasushi Tsuji},
title = {Cu-Catalyzed Borylative and Silylative Transformations of Allenes: Use of β-Functionalized Allyl Copper Intermediates in Organic Synthesis},
journal = {Synthesis},
year = {2018},
volume = {50},
publisher = {Georg Thieme Verlag KG},
month = {mar},
url = {https://doi.org/10.1055/s-0036-1591777},
number = {09},
pages = {1737--1749},
doi = {10.1055/s-0036-1591777}
}
MLA
Cite this
MLA Copy
Fujihara, Tetsuaki, and Yasushi Tsuji. “Cu-Catalyzed Borylative and Silylative Transformations of Allenes: Use of β-Functionalized Allyl Copper Intermediates in Organic Synthesis.” Synthesis, vol. 50, no. 09, Mar. 2018, pp. 1737-1749. https://doi.org/10.1055/s-0036-1591777.