Cu-Catalyzed Borylative and Silylative Transformations of Allenes: Use of β-Functionalized Allyl Copper Intermediates in Organic Synthesis
Тип публикации: Journal Article
Дата публикации: 2018-03-20
SCImago Q2
WOS Q3
БС2
SJR: 0.443
CiteScore: 4.3
Impact factor: 2.2
ISSN: 00397881, 1437210X
Catalysis
Organic Chemistry
Краткое описание
Herein, copper-catalyzed borylative and silylative transformations of allenes using borylcopper or silylcopper as the active catalytic species are described. First, the synthesis and characterization of borylcopper and silylcopper complexes are briefly introduced. Next, the borylative transformations of allenes are summarized including hydroboration, carboboration, and borylative allylation of carbonyl compounds. We next deal with the silylative transformations of allenes such as hydrosilylation, carbosilylation, and silylative allylation of carbonyl compounds.
1 Introduction
2 Synthesis of Borylcopper and Silylcopper Complexes
3 Borylative Transformations
4 Silylative Transformations
5 Conclusions and Future Outlook
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Fujihara T., Tsuji Y. Cu-Catalyzed Borylative and Silylative Transformations of Allenes: Use of β-Functionalized Allyl Copper Intermediates in Organic Synthesis // Synthesis. 2018. Vol. 50. No. 09. pp. 1737-1749.
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Fujihara T., Tsuji Y. Cu-Catalyzed Borylative and Silylative Transformations of Allenes: Use of β-Functionalized Allyl Copper Intermediates in Organic Synthesis // Synthesis. 2018. Vol. 50. No. 09. pp. 1737-1749.
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TY - JOUR
DO - 10.1055/s-0036-1591777
UR - https://doi.org/10.1055/s-0036-1591777
TI - Cu-Catalyzed Borylative and Silylative Transformations of Allenes: Use of β-Functionalized Allyl Copper Intermediates in Organic Synthesis
T2 - Synthesis
AU - Fujihara, Tetsuaki
AU - Tsuji, Yasushi
PY - 2018
DA - 2018/03/20
PB - Georg Thieme Verlag KG
SP - 1737-1749
IS - 09
VL - 50
SN - 0039-7881
SN - 1437-210X
ER -
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@article{2018_Fujihara,
author = {Tetsuaki Fujihara and Yasushi Tsuji},
title = {Cu-Catalyzed Borylative and Silylative Transformations of Allenes: Use of β-Functionalized Allyl Copper Intermediates in Organic Synthesis},
journal = {Synthesis},
year = {2018},
volume = {50},
publisher = {Georg Thieme Verlag KG},
month = {mar},
url = {https://doi.org/10.1055/s-0036-1591777},
number = {09},
pages = {1737--1749},
doi = {10.1055/s-0036-1591777}
}
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MLA
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Fujihara, Tetsuaki, and Yasushi Tsuji. “Cu-Catalyzed Borylative and Silylative Transformations of Allenes: Use of β-Functionalized Allyl Copper Intermediates in Organic Synthesis.” Synthesis, vol. 50, no. 09, Mar. 2018, pp. 1737-1749. https://doi.org/10.1055/s-0036-1591777.
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