, volume 50 , issue 15 , pages 2908-2914

Irradiation-Induced Palladium-Catalyzed Direct C–H Alkylation of Heteroarenes with Tertiary and Secondary Alkyl Bromides

Rui Shang ^{1, 2}

Yao Fu ¹

Guang Zu Wang ¹

Hide authors affiliations Show authors affiliations: 2 affiliations

Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, iChEM, Department of Chemistry, University of Science and Technology of China |

Department of Chemistry, School of Science, The University of Tokyo |

Publication type: Journal Article

Publication date: 2018-04-25

Georg Thieme Verlag KG

Synthesis

scimago Q2

wos Q2

SJR: 0.559

CiteScore: 4.6

Impact factor: 2.3

ISSN: 00397881, 1437210X

DOI: 10.1055/s-0036-1592000

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Catalysis

Organic Chemistry

Abstract

A palladium catalyst in combination with two types of phosphine ligands efficiently catalyzes direct C–H alkylation of heteroarenes with secondary and tertiary alkyl bromides under irradiation conditions. Irradiation of blue light-emitting diodes (blue LEDs) effectively excites phosphine-ligated palladium catalyst to facilitate oxidative addition with alkyl bromides, and also excites the alkylpalladium species to enable the generation of alkyl radicals to react with heteroarenes.

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1 citation

Karlinskii Bogdan

PhD in Chemistry

17 publications, 237 citations, 82 reviews

h-index: 9

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Tula State University

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Shang R. et al. Irradiation-Induced Palladium-Catalyzed Direct C–H Alkylation of Heteroarenes with Tertiary and Secondary Alkyl Bromides // Synthesis. 2018. Vol. 50. No. 15. pp. 2908-2914.

GOST all authors (up to 50) Copy

Shang R., Fu Y., Wang G. Z. Irradiation-Induced Palladium-Catalyzed Direct C–H Alkylation of Heteroarenes with Tertiary and Secondary Alkyl Bromides // Synthesis. 2018. Vol. 50. No. 15. pp. 2908-2914.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1055/s-0036-1592000

UR - https://doi.org/10.1055/s-0036-1592000

TI - Irradiation-Induced Palladium-Catalyzed Direct C–H Alkylation of Heteroarenes with Tertiary and Secondary Alkyl Bromides

T2 - Synthesis

AU - Shang, Rui

AU - Fu, Yao

AU - Wang, Guang Zu

PY - 2018

DA - 2018/04/25

PB - Georg Thieme Verlag KG

SP - 2908-2914

IS - 15

VL - 50

SN - 0039-7881

SN - 1437-210X

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2018_Shang,

author = {Rui Shang and Yao Fu and Guang Zu Wang},

title = {Irradiation-Induced Palladium-Catalyzed Direct C–H Alkylation of Heteroarenes with Tertiary and Secondary Alkyl Bromides},

journal = {Synthesis},

year = {2018},

volume = {50},

publisher = {Georg Thieme Verlag KG},

month = {apr},

url = {https://doi.org/10.1055/s-0036-1592000},

number = {15},

pages = {2908--2914},

doi = {10.1055/s-0036-1592000}

}

MLA

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MLA Copy

Shang, Rui, et al. “Irradiation-Induced Palladium-Catalyzed Direct C–H Alkylation of Heteroarenes with Tertiary and Secondary Alkyl Bromides.” Synthesis, vol. 50, no. 15, Apr. 2018, pp. 2908-2914. https://doi.org/10.1055/s-0036-1592000.

Publisher

Georg Thieme Verlag KG

Journal

Synthesis

scimago Q2

wos Q2

SJR

0.559

CiteScore

4.6

Impact factor

2.3

ISSN

00397881 (Print)

1437210X (Electronic)