Synthesis, volume 50, issue 19, pages 3749-3786
Recent Advances in Total Synthesis via Metathesis Reactions
1
Department of Organic Chemistry, Faculty of Sciences, University of Málaga
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Publication type: Journal Article
Publication date: 2018-07-18
Catalysis
Organic Chemistry
Abstract
The metathesis reactions, in their various versions, have become a powerful and extremely valuable tool for the formation of carbon–carbon bonds in organic synthesis. The plethora of available catalysts to perform these reactions, combined with the various transformations that can be accomplished, have positioned the metathesis processes as one of the most important reactions of this century. In this review, we highlight the most relevant synthetic contributions published between 2012 and early 2018 in the field of total synthesis, reflecting the state of the art of this chemistry and demonstrating the significant synthetic potential of these methodologies.
1 Introduction
2 Alkene Metathesis in Total Synthesis
2.1 Total Synthesis Based on a Ring-Closing-Metathesis Reaction
2.2 Total Synthesis Based on a Cross-Metathesis Reaction
2.3 Strategies for Selective and Efficient Metathesis Reactions of Alkenes
2.3.1 Temporary Tethered Ring-Closing Metathesis
2.3.2 Relay Ring-Closing Metathesis
2.3.3 Stereoselective Alkene Metathesis
2.3.4 Alkene Metathesis in Tandem Reactions
3 Enyne Metathesis in Total Synthesis
3.1 Total Syntheses Based on a Ring-Closing Enyne-Metathesis Reaction
3.2 Total Syntheses Based on an Enyne Cross-Metathesis Reaction
3.3 Enyne Metathesis in Tandem Reactions
4 Alkyne Metathesis in Total Synthesis
4.1 Total Synthesis Based on a Ring-Closing Alkyne-Metathesis Reaction
4.2 Other Types of Alkyne-Metathesis Reactions
5 Conclusions
Top-30
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1 publication, 1.47%
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1 publication, 1.47%
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1 publication, 1.47%
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1 publication, 1.47%
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Citations by publishers
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Wiley
26 publications, 38.24%
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American Chemical Society (ACS)
23 publications, 33.82%
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Elsevier
6 publications, 8.82%
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Royal Society of Chemistry (RSC)
3 publications, 4.41%
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Beilstein-Institut
2 publications, 2.94%
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Multidisciplinary Digital Publishing Institute (MDPI)
2 publications, 2.94%
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Thieme
2 publications, 2.94%
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Society of Synthetic Organic Chemistry
1 publication, 1.47%
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The Chemical Society of Japan
1 publication, 1.47%
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The Japan Institute of Heterocyclic Chemistry
1 publication, 1.47%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 1.47%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Sarabia F., Cheng Sánchez I. Recent Advances in Total Synthesis via Metathesis Reactions // Synthesis. 2018. Vol. 50. No. 19. pp. 3749-3786.
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Sarabia F., Cheng Sánchez I. Recent Advances in Total Synthesis via Metathesis Reactions // Synthesis. 2018. Vol. 50. No. 19. pp. 3749-3786.
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TY - JOUR
DO - 10.1055/s-0037-1610206
UR - https://doi.org/10.1055/s-0037-1610206
TI - Recent Advances in Total Synthesis via Metathesis Reactions
T2 - Synthesis
AU - Sarabia, Francisco
AU - Cheng Sánchez, Iván
PY - 2018
DA - 2018/07/18 00:00:00
PB - Thieme
SP - 3749-3786
IS - 19
VL - 50
SN - 0039-7881
SN - 1437-210X
ER -
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@article{2018_Sarabia,
author = {Francisco Sarabia and Iván Cheng Sánchez},
title = {Recent Advances in Total Synthesis via Metathesis Reactions},
journal = {Synthesis},
year = {2018},
volume = {50},
publisher = {Thieme},
month = {jul},
url = {https://doi.org/10.1055/s-0037-1610206},
number = {19},
pages = {3749--3786},
doi = {10.1055/s-0037-1610206}
}
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MLA
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Sarabia, Francisco, and Iván Cheng Sánchez. “Recent Advances in Total Synthesis via Metathesis Reactions.” Synthesis, vol. 50, no. 19, Jul. 2018, pp. 3749-3786. https://doi.org/10.1055/s-0037-1610206.