Molecular Structures of PCl4F, PCl3F2, PCl2F3, and PF5: Infrared and Low‐Temperature Raman Vibrational Spectra
1
BELL TELEPHONE LABORATORIES, INCORPORATED, MURRAY HILL, NEW JERSEY
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Publication type: Journal Article
Publication date: 1964-08-01
scimago Q1
wos Q2
SJR: 0.819
CiteScore: 5.3
Impact factor: 3.1
ISSN: 00219606, 10897690
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
Molecular structures of PCl4F, PCl3F2, PCl2F3, and PF5 are derived from vapor-state infrared spectra (2000–250 cm—1) and low-temperature liquid-state Raman displacements (Δν=50–1200 cm—1) together with qualitative polarization measurements. All of the compounds appear to have a basic trigonal bipyramidal framework.
The spectra of PCl4F are best interpreted in terms of a C3v structure in which the fluorine atom occupies an axial site; in PCl3F2 (D3h point group) the fluorine atoms also assume axial positions. For PCl2F3, the symmetrical D3h structure is shown to be incorrect. Available evidence supports the C2v structure in which the fluorine atoms appear in one equatorial and two axial sites. Phosphorus pentafluoride is found to have a regular trigonal bipyramidal structure.
Complete vibrational assignments are made in terms of the normal modes and thermodynamic functions are evaluated for PCl5, PCl3F2, and PF5.
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Griffiths J. E., CARTER R. P., Holmes R. R. Molecular Structures of PCl4F, PCl3F2, PCl2F3, and PF5: Infrared and Low‐Temperature Raman Vibrational Spectra // Journal of Chemical Physics. 1964. Vol. 41. No. 3. pp. 863-876.
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Griffiths J. E., CARTER R. P., Holmes R. R. Molecular Structures of PCl4F, PCl3F2, PCl2F3, and PF5: Infrared and Low‐Temperature Raman Vibrational Spectra // Journal of Chemical Physics. 1964. Vol. 41. No. 3. pp. 863-876.
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TY - JOUR
DO - 10.1063/1.1725974
UR - https://doi.org/10.1063/1.1725974
TI - Molecular Structures of PCl4F, PCl3F2, PCl2F3, and PF5: Infrared and Low‐Temperature Raman Vibrational Spectra
T2 - Journal of Chemical Physics
AU - Griffiths, James E.
AU - CARTER, RICHARD P.
AU - Holmes, Robert R.
PY - 1964
DA - 1964/08/01
PB - AIP Publishing
SP - 863-876
IS - 3
VL - 41
SN - 0021-9606
SN - 1089-7690
ER -
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@article{1964_Griffiths,
author = {James E. Griffiths and RICHARD P. CARTER and Robert R. Holmes},
title = {Molecular Structures of PCl4F, PCl3F2, PCl2F3, and PF5: Infrared and Low‐Temperature Raman Vibrational Spectra},
journal = {Journal of Chemical Physics},
year = {1964},
volume = {41},
publisher = {AIP Publishing},
month = {aug},
url = {https://doi.org/10.1063/1.1725974},
number = {3},
pages = {863--876},
doi = {10.1063/1.1725974}
}
Cite this
MLA
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Griffiths, James E., et al. “Molecular Structures of PCl4F, PCl3F2, PCl2F3, and PF5: Infrared and Low‐Temperature Raman Vibrational Spectra.” Journal of Chemical Physics, vol. 41, no. 3, Aug. 1964, pp. 863-876. https://doi.org/10.1063/1.1725974.