Intramolecular Reaction in Polycondensations. I. The Theory of Linear Systems
Тип публикации: Journal Article
Дата публикации: 1950-12-01
scimago Q1
wos Q2
БС2
SJR: 0.819
CiteScore: 5.3
Impact factor: 3.1
ISSN: 00219606, 10897690
Physical and Theoretical Chemistry
General Physics and Astronomy
Краткое описание
For three types of linear polycondensing systems, equilibrium molecular size distributions, including rings as allowable species, are derived. Average molecular weights and amounts of ring and chain fractions are calculated therefrom. The fractions of rings are shown to increase with dilution, and with molecular weight. It is shown that beyond a critical dilution it is sometimes possible to obtain 100 percent yield of rings by driving the condensation to completion. Detailed calculations are made for two important cases corresponding to condensations of the decamethylene glycol-adipic acid type: (1) for equimolar amounts of the two monomers, and (2) unequal amounts, with one monomer type completely reacted.
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ГОСТ
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Jacobson H., Stockmayer W. H. Intramolecular Reaction in Polycondensations. I. The Theory of Linear Systems // Journal of Chemical Physics. 1950. Vol. 18. No. 12. pp. 1600-1606.
ГОСТ со всеми авторами (до 50)
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Jacobson H., Stockmayer W. H. Intramolecular Reaction in Polycondensations. I. The Theory of Linear Systems // Journal of Chemical Physics. 1950. Vol. 18. No. 12. pp. 1600-1606.
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RIS
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TY - JOUR
DO - 10.1063/1.1747547
UR - https://doi.org/10.1063/1.1747547
TI - Intramolecular Reaction in Polycondensations. I. The Theory of Linear Systems
T2 - Journal of Chemical Physics
AU - Jacobson, Homer
AU - Stockmayer, Walter H
PY - 1950
DA - 1950/12/01
PB - AIP Publishing
SP - 1600-1606
IS - 12
VL - 18
SN - 0021-9606
SN - 1089-7690
ER -
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BibTex (до 50 авторов)
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@article{1950_Jacobson,
author = {Homer Jacobson and Walter H Stockmayer},
title = {Intramolecular Reaction in Polycondensations. I. The Theory of Linear Systems},
journal = {Journal of Chemical Physics},
year = {1950},
volume = {18},
publisher = {AIP Publishing},
month = {dec},
url = {https://doi.org/10.1063/1.1747547},
number = {12},
pages = {1600--1606},
doi = {10.1063/1.1747547}
}
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MLA
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Jacobson, Homer, and Walter H Stockmayer. “Intramolecular Reaction in Polycondensations. I. The Theory of Linear Systems.” Journal of Chemical Physics, vol. 18, no. 12, Dec. 1950, pp. 1600-1606. https://doi.org/10.1063/1.1747547.