Infrared absorption and electron paramagnetic resonance studies of vinyl radical in noble-gas matrices
Тип публикации: Journal Article
Дата публикации: 2005-08-08
scimago Q1
wos Q2
БС2
SJR: 0.819
CiteScore: 5.3
Impact factor: 3.1
ISSN: 00219606, 10897690
PubMed ID:
16122319
Physical and Theoretical Chemistry
General Physics and Astronomy
Краткое описание
Vinyl radicals produced by annealing-induced reaction of mobilized hydrogen atoms with acetylene molecules in solid noble-gas matrices (Ar, Kr, and Xe) were characterized by Fourier transform infrared and electron paramagnetic resonance (EPR) spectroscopies. The hydrogen atoms were generated from acetylene by UV photolysis or fast electron irradiation. Two vibrational modes of the vinyl radical (ν7 and ν5) were assigned in IR absorption studies. The assignment is based on data for various isotopic substitutions (D and C13) and confirmed by comparison with the EPR measurements and density-functional theory calculations. The data on the ν7 mode is in agreement with previous experimental and theoretical results whereas the ν5 frequency agrees well with the computational data but conflicts with the gas-phase IR emission results.
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Tanskanen H. et al. Infrared absorption and electron paramagnetic resonance studies of vinyl radical in noble-gas matrices // Journal of Chemical Physics. 2005. Vol. 123. No. 6. p. 64318.
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Tanskanen H., Khriachtchev L., Räsänen M., Feldman V. I., Sukhov F. F., Orlov A. Yu., Tyurin D. A. Infrared absorption and electron paramagnetic resonance studies of vinyl radical in noble-gas matrices // Journal of Chemical Physics. 2005. Vol. 123. No. 6. p. 64318.
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TY - JOUR
DO - 10.1063/1.2000907
UR - https://pubs.aip.org/jcp/article/123/6/064318/933071/Infrared-absorption-and-electron-paramagnetic
TI - Infrared absorption and electron paramagnetic resonance studies of vinyl radical in noble-gas matrices
T2 - Journal of Chemical Physics
AU - Tanskanen, Hanna
AU - Khriachtchev, Leonid
AU - Räsänen, Markku
AU - Feldman, Vladimir I
AU - Sukhov, Fedor F
AU - Orlov, Aleksei Yu
AU - Tyurin, Daniil A
PY - 2005
DA - 2005/08/08
PB - AIP Publishing
SP - 64318
IS - 6
VL - 123
PMID - 16122319
SN - 0021-9606
SN - 1089-7690
ER -
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@article{2005_Tanskanen,
author = {Hanna Tanskanen and Leonid Khriachtchev and Markku Räsänen and Vladimir I Feldman and Fedor F Sukhov and Aleksei Yu Orlov and Daniil A Tyurin},
title = {Infrared absorption and electron paramagnetic resonance studies of vinyl radical in noble-gas matrices},
journal = {Journal of Chemical Physics},
year = {2005},
volume = {123},
publisher = {AIP Publishing},
month = {aug},
url = {https://pubs.aip.org/jcp/article/123/6/064318/933071/Infrared-absorption-and-electron-paramagnetic},
number = {6},
pages = {64318},
doi = {10.1063/1.2000907}
}
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Tanskanen, Hanna, et al. “Infrared absorption and electron paramagnetic resonance studies of vinyl radical in noble-gas matrices.” Journal of Chemical Physics, vol. 123, no. 6, Aug. 2005, p. 64318. https://pubs.aip.org/jcp/article/123/6/064318/933071/Infrared-absorption-and-electron-paramagnetic.
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