Effect of diamagnetic Ca, Sr, Pb, and Ba substitution on the crystal structure and multiferroic properties of the BiFeO3 perovskite
V A Khomchenko
1
,
D. A. Kiselev
1
,
J.-M. Vieira
1
,
Li Jian
1
,
A. L. KHOLKIN
1
,
A.M.L Lopes
2
,
Y. G. Pogorelov
2
,
J. P. Araujo
2
,
M. Maglione
3
2
Publication type: Journal Article
Publication date: 2008-01-15
scimago Q2
wos Q3
SJR: 0.580
CiteScore: 5.1
Impact factor: 2.5
ISSN: 00218979, 10897550
General Physics and Astronomy
Abstract
In this work, we studied the effect of heterovalent Ca, Sr, Pb, and Ba substitution on the crystal structure, dielectric, local ferroelectric, and magnetic properties of the BiFeO3 multiferroic perovskite. Ceramic solid solutions with the general formula Bi0.7A0.3FeO3 (A is a doping element) were prepared and characterized by x-ray diffraction, dielectric, piezoresponse force microscopy (PFM), and magnetic measurements. It is shown that the crystal structure of the compounds is described within the space group R3c, permitting the spontaneous polarization, whose existence was confirmed by the PFM data. Magnetic properties of the solid solutions are determined by the ionic radius of the substituting element. Experimental results suggest that the increase in the radius of the A-site ion leads to the effective suppression of the spiral spin structure of BiFeO3, resulting in the appearance of net magnetization.
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Total citations:
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Khomchenko V. A. et al. Effect of diamagnetic Ca, Sr, Pb, and Ba substitution on the crystal structure and multiferroic properties of the BiFeO3 perovskite // Journal of Applied Physics. 2008. Vol. 103. No. 2. p. 24105.
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Khomchenko V. A., Kiselev D. A., Vieira J., Jian L., KHOLKIN A. L., Lopes A., Pogorelov Y. G., Araujo J. P., Maglione M. Effect of diamagnetic Ca, Sr, Pb, and Ba substitution on the crystal structure and multiferroic properties of the BiFeO3 perovskite // Journal of Applied Physics. 2008. Vol. 103. No. 2. p. 24105.
Cite this
RIS
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TY - JOUR
DO - 10.1063/1.2836802
UR - https://doi.org/10.1063/1.2836802
TI - Effect of diamagnetic Ca, Sr, Pb, and Ba substitution on the crystal structure and multiferroic properties of the BiFeO3 perovskite
T2 - Journal of Applied Physics
AU - Khomchenko, V A
AU - Kiselev, D. A.
AU - Vieira, J.-M.
AU - Jian, Li
AU - KHOLKIN, A. L.
AU - Lopes, A.M.L
AU - Pogorelov, Y. G.
AU - Araujo, J. P.
AU - Maglione, M.
PY - 2008
DA - 2008/01/15
PB - AIP Publishing
SP - 24105
IS - 2
VL - 103
SN - 0021-8979
SN - 1089-7550
ER -
Cite this
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@article{2008_Khomchenko,
author = {V A Khomchenko and D. A. Kiselev and J.-M. Vieira and Li Jian and A. L. KHOLKIN and A.M.L Lopes and Y. G. Pogorelov and J. P. Araujo and M. Maglione},
title = {Effect of diamagnetic Ca, Sr, Pb, and Ba substitution on the crystal structure and multiferroic properties of the BiFeO3 perovskite},
journal = {Journal of Applied Physics},
year = {2008},
volume = {103},
publisher = {AIP Publishing},
month = {jan},
url = {https://doi.org/10.1063/1.2836802},
number = {2},
pages = {24105},
doi = {10.1063/1.2836802}
}
Cite this
MLA
Copy
Khomchenko, V. A., et al. “Effect of diamagnetic Ca, Sr, Pb, and Ba substitution on the crystal structure and multiferroic properties of the BiFeO3 perovskite.” Journal of Applied Physics, vol. 103, no. 2, Jan. 2008, p. 24105. https://doi.org/10.1063/1.2836802.