volume 62 issue 5 pages 1761-1767

Properties of carbon clusters in TNT detonation products: Graphite‐diamond transition

Publication typeJournal Article
Publication date1987-09-01
scimago Q2
wos Q3
SJR0.580
CiteScore5.1
Impact factor2.5
ISSN00218979, 10897550
General Physics and Astronomy
Abstract

The thermodynamic properties of condensed carbon in the detonation products of TNT have been analyzed with a statistical mechanical model. The calculations show that the heat of formation of diamondlike particles in detonation products is increased by 1–2 kcal/mol (0.04–0.08 eV), relative to that of the graphitic or carbynelike low-pressure phase. The density of the low-pressure phase also appears to be about 10% higher than that of graphite. The short condensation times of 10−7–10−8 s suggest carbon clusters with a high surface energy. The heat of formation indicates cluster sizes of about 100 Å.

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GOST |
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GOST Copy
Van Thiel M., Ree F. H. Properties of carbon clusters in TNT detonation products: Graphite‐diamond transition // Journal of Applied Physics. 1987. Vol. 62. No. 5. pp. 1761-1767.
GOST all authors (up to 50) Copy
Van Thiel M., Ree F. H. Properties of carbon clusters in TNT detonation products: Graphite‐diamond transition // Journal of Applied Physics. 1987. Vol. 62. No. 5. pp. 1761-1767.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1063/1.339575
UR - https://doi.org/10.1063/1.339575
TI - Properties of carbon clusters in TNT detonation products: Graphite‐diamond transition
T2 - Journal of Applied Physics
AU - Van Thiel, Mathias
AU - Ree, Francis H.
PY - 1987
DA - 1987/09/01
PB - AIP Publishing
SP - 1761-1767
IS - 5
VL - 62
SN - 0021-8979
SN - 1089-7550
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{1987_Van Thiel,
author = {Mathias Van Thiel and Francis H. Ree},
title = {Properties of carbon clusters in TNT detonation products: Graphite‐diamond transition},
journal = {Journal of Applied Physics},
year = {1987},
volume = {62},
publisher = {AIP Publishing},
month = {sep},
url = {https://doi.org/10.1063/1.339575},
number = {5},
pages = {1761--1767},
doi = {10.1063/1.339575}
}
MLA
Cite this
MLA Copy
Van Thiel, Mathias, and Francis H. Ree. “Properties of carbon clusters in TNT detonation products: Graphite‐diamond transition.” Journal of Applied Physics, vol. 62, no. 5, Sep. 1987, pp. 1761-1767. https://doi.org/10.1063/1.339575.