Unimolecular processes in vibrationally highly excited cycloheptatrienes. III. Direct k (E) measurements after laser excitation
Тип публикации: Journal Article
Дата публикации: 1983-07-01
SCImago Q1
WOS Q1
БС2
SJR: 0.877
CiteScore: 5.3
Impact factor: 3.7
ISSN: 00219606, 10897690
Physical and Theoretical Chemistry
General Physics and Astronomy
Краткое описание
Vibrationally highly excited substituted cycloheptatrienes in their electronic ground states have been prepared by single photon UV laser excitation and subsequent internal conversion. The unimolecular isomerizations of these species have been followed by time resolved UV absorption spectroscopy. The specific rate constants k (E) could be obtained directly at low pressures for methyl-, ethyl-, and isopropyl-substituted cycloheptatrienes. The influence of collisions on the rate of product formation has been elucidated as well. The results are compared with thermal and steady-state photoisomerization experiments. Statistical theories of unimolecular reactions can fully account for all results.
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ГОСТ
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Hippler H. et al. Unimolecular processes in vibrationally highly excited cycloheptatrienes. III. Direct k (E) measurements after laser excitation // Journal of Chemical Physics. 1983. Vol. 79. No. 1. pp. 239-246.
ГОСТ со всеми авторами (до 50)
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Hippler H., Luther K., Troe J., Wendelken H. J. Unimolecular processes in vibrationally highly excited cycloheptatrienes. III. Direct k (E) measurements after laser excitation // Journal of Chemical Physics. 1983. Vol. 79. No. 1. pp. 239-246.
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RIS
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TY - JOUR
DO - 10.1063/1.445563
UR - https://doi.org/10.1063/1.445563
TI - Unimolecular processes in vibrationally highly excited cycloheptatrienes. III. Direct k (E) measurements after laser excitation
T2 - Journal of Chemical Physics
AU - Hippler, H.
AU - Luther, K.
AU - Troe, J
AU - Wendelken, H J
PY - 1983
DA - 1983/07/01
PB - AIP Publishing
SP - 239-246
IS - 1
VL - 79
SN - 0021-9606
SN - 1089-7690
ER -
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BibTex (до 50 авторов)
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@article{1983_Hippler,
author = {H. Hippler and K. Luther and J Troe and H J Wendelken},
title = {Unimolecular processes in vibrationally highly excited cycloheptatrienes. III. Direct k (E) measurements after laser excitation},
journal = {Journal of Chemical Physics},
year = {1983},
volume = {79},
publisher = {AIP Publishing},
month = {jul},
url = {https://doi.org/10.1063/1.445563},
number = {1},
pages = {239--246},
doi = {10.1063/1.445563}
}
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MLA
Скопировать
Hippler, H., et al. “Unimolecular processes in vibrationally highly excited cycloheptatrienes. III. Direct k (E) measurements after laser excitation.” Journal of Chemical Physics, vol. 79, no. 1, Jul. 1983, pp. 239-246. https://doi.org/10.1063/1.445563.
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