Reversible and irreversible thermochromic phase transitions in single crystals of polydiacetylenes substituted with alkyl‐urethanes
Тип публикации: Journal Article
Дата публикации: 1990-06-15
scimago Q1
wos Q2
БС2
SJR: 0.819
CiteScore: 5.3
Impact factor: 3.1
ISSN: 00219606, 10897690
Physical and Theoretical Chemistry
General Physics and Astronomy
Краткое описание
Reversible transitions between the two spectroscopically distinct phases (A and B phases) have been investigated for a new family of polydiacetylenes (PDAs) substituted with side groups of alkyl-urethane [−(CH2)4OCONH(CH2)n−1CH3:n=1−10]. Measurements of optical spectra as well as x-ray and calorimetric studies have revealed the first-order-like phase transitions in a series of PDAs with n=1–10 which are associated with an n-dependent thermal hysteresis ranging from 0 to 60 K in width. It has been found that the thermochromic changes become irreversible in all these PDAs once the hydrogen bond chains in the side groups are interrupted by heating beyond the polymer melting temperature.
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Koshihara S. et al. Reversible and irreversible thermochromic phase transitions in single crystals of polydiacetylenes substituted with alkyl‐urethanes // Journal of Chemical Physics. 1990. Vol. 92. No. 12. pp. 7581-7588.
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Koshihara S., Tokura Y., Takeda K., Koda T., Kobayashi A. Reversible and irreversible thermochromic phase transitions in single crystals of polydiacetylenes substituted with alkyl‐urethanes // Journal of Chemical Physics. 1990. Vol. 92. No. 12. pp. 7581-7588.
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TY - JOUR
DO - 10.1063/1.458195
UR - https://doi.org/10.1063/1.458195
TI - Reversible and irreversible thermochromic phase transitions in single crystals of polydiacetylenes substituted with alkyl‐urethanes
T2 - Journal of Chemical Physics
AU - Koshihara, Shin-ya
AU - Tokura, Yoshinori
AU - Takeda, Kenji
AU - Koda, Takao
AU - Kobayashi, Akiko
PY - 1990
DA - 1990/06/15
PB - AIP Publishing
SP - 7581-7588
IS - 12
VL - 92
SN - 0021-9606
SN - 1089-7690
ER -
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@article{1990_Koshihara,
author = {Shin-ya Koshihara and Yoshinori Tokura and Kenji Takeda and Takao Koda and Akiko Kobayashi},
title = {Reversible and irreversible thermochromic phase transitions in single crystals of polydiacetylenes substituted with alkyl‐urethanes},
journal = {Journal of Chemical Physics},
year = {1990},
volume = {92},
publisher = {AIP Publishing},
month = {jun},
url = {https://doi.org/10.1063/1.458195},
number = {12},
pages = {7581--7588},
doi = {10.1063/1.458195}
}
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Koshihara, Shin-ya, et al. “Reversible and irreversible thermochromic phase transitions in single crystals of polydiacetylenes substituted with alkyl‐urethanes.” Journal of Chemical Physics, vol. 92, no. 12, Jun. 1990, pp. 7581-7588. https://doi.org/10.1063/1.458195.