volume 7 issue 2 pages 58-59

Synthesis of 4-diazo-3,5-dinitropyrazole and characteristic features of its behaviour towards nucleophiles.

Publication typeJournal Article
Publication date1997-01-01
scimago Q3
wos Q3
SJR0.305
CiteScore3.0
Impact factor1.7
ISSN09599436, 1364551X
General Chemistry
Abstract
Diazopyrazole containing two nitro groups in the ring - 4-diazo-3,5-dinitropyrazole - has been synthesised for the first time by diazotisation of the corresponding aminodinitropyrazole. 4-Diazo-3,5-dinitropyrazole reacts with salts of methylene-active compounds, CH2(CN)NO2 and CH2(COCH3)2, to give azo coupling products, whereas its interaction with nucleophiles such as Br-, N3 or H2O(H+) involves replacement of one of the nitro groups yielding 4-diazo-3-R-5-nitropyrazoles.
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GOST Copy
Dalinger I. L., Cherkasova T. I., Shevelev S. A. Synthesis of 4-diazo-3,5-dinitropyrazole and characteristic features of its behaviour towards nucleophiles. // Mendeleev Communications. 1997. Vol. 7. No. 2. pp. 58-59.
GOST all authors (up to 50) Copy
Dalinger I. L., Cherkasova T. I., Shevelev S. A. Synthesis of 4-diazo-3,5-dinitropyrazole and characteristic features of its behaviour towards nucleophiles. // Mendeleev Communications. 1997. Vol. 7. No. 2. pp. 58-59.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1070/MC1997v007n02ABEH000670
UR - https://doi.org/10.1070/MC1997v007n02ABEH000670
TI - Synthesis of 4-diazo-3,5-dinitropyrazole and characteristic features of its behaviour towards nucleophiles.
T2 - Mendeleev Communications
AU - Dalinger, Igor L
AU - Cherkasova, Tatyana I
AU - Shevelev, Svyatoslav A.
PY - 1997
DA - 1997/01/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 58-59
IS - 2
VL - 7
SN - 0959-9436
SN - 1364-551X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{1997_Dalinger,
author = {Igor L Dalinger and Tatyana I Cherkasova and Svyatoslav A. Shevelev},
title = {Synthesis of 4-diazo-3,5-dinitropyrazole and characteristic features of its behaviour towards nucleophiles.},
journal = {Mendeleev Communications},
year = {1997},
volume = {7},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {jan},
url = {https://doi.org/10.1070/MC1997v007n02ABEH000670},
number = {2},
pages = {58--59},
doi = {10.1070/MC1997v007n02ABEH000670}
}
MLA
Cite this
MLA Copy
Dalinger, Igor L., et al. “Synthesis of 4-diazo-3,5-dinitropyrazole and characteristic features of its behaviour towards nucleophiles..” Mendeleev Communications, vol. 7, no. 2, Jan. 1997, pp. 58-59. https://doi.org/10.1070/MC1997v007n02ABEH000670.