A novel stereoselective and catalytic CC coupling reaction: acetylene dimerization accompanied by addition of iodine to yield (E,E)-1,4-diiodobuta-1,3-diene in the PtIV–I––I2–MeOH system
Тип публикации: Journal Article
Дата публикации: 1997-01-01
SCImago Q3
WOS Q3
БС1
SJR: 0.276
CiteScore: 2.7
Impact factor: 1.4
ISSN: 09599436, 1364551X
General Chemistry
Краткое описание
A new catalytic reaction-dimerization of acetylene accompanied by addition of iodine to yield (E,E)-1,4-diiodobuta-1,3-diene at 30°C in a methanolic solution of NaI, PtIV and I2 has been found; a plausible reaction mechanism involves intermediate formation of a cis-divinyl derivative of platinum(IV) through two subsequent triple bond iodoplatination steps followed by reductive elimination of the final product.
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Mitchenko S. A. et al. A novel stereoselective and catalytic CC coupling reaction: acetylene dimerization accompanied by addition of iodine to yield (E,E)-1,4-diiodobuta-1,3-diene in the PtIV–I––I2–MeOH system // Mendeleev Communications. 1997. Vol. 7. No. 4. pp. 130-131.
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Mitchenko S. A., Ananikov V. P., Beletskaya I. P., Ustynyuk Y. A. A novel stereoselective and catalytic CC coupling reaction: acetylene dimerization accompanied by addition of iodine to yield (E,E)-1,4-diiodobuta-1,3-diene in the PtIV–I––I2–MeOH system // Mendeleev Communications. 1997. Vol. 7. No. 4. pp. 130-131.
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TY - JOUR
DO - 10.1070/MC1997v007n04ABEH000715
UR - https://doi.org/10.1070/MC1997v007n04ABEH000715
TI - A novel stereoselective and catalytic CC coupling reaction: acetylene dimerization accompanied by addition of iodine to yield (E,E)-1,4-diiodobuta-1,3-diene in the PtIV–I––I2–MeOH system
T2 - Mendeleev Communications
AU - Mitchenko, Sergey A
AU - Ananikov, Valentine P
AU - Beletskaya, Irina P.
AU - Ustynyuk, Yuri A.
PY - 1997
DA - 1997/01/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 130-131
IS - 4
VL - 7
SN - 0959-9436
SN - 1364-551X
ER -
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BibTex (до 50 авторов)
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@article{1997_Mitchenko,
author = {Sergey A Mitchenko and Valentine P Ananikov and Irina P. Beletskaya and Yuri A. Ustynyuk},
title = {A novel stereoselective and catalytic CC coupling reaction: acetylene dimerization accompanied by addition of iodine to yield (E,E)-1,4-diiodobuta-1,3-diene in the PtIV–I––I2–MeOH system},
journal = {Mendeleev Communications},
year = {1997},
volume = {7},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {jan},
url = {https://doi.org/10.1070/MC1997v007n04ABEH000715},
number = {4},
pages = {130--131},
doi = {10.1070/MC1997v007n04ABEH000715}
}
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MLA
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Mitchenko, Sergey A., et al. “A novel stereoselective and catalytic CC coupling reaction: acetylene dimerization accompanied by addition of iodine to yield (E,E)-1,4-diiodobuta-1,3-diene in the PtIV–I––I2–MeOH system.” Mendeleev Communications, vol. 7, no. 4, Jan. 1997, pp. 130-131. https://doi.org/10.1070/MC1997v007n04ABEH000715.
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