The first example of a reversibly reducible CoII complex with an anionic 2-thiohydantoin-type ligand
Publication type: Journal Article
Publication date: 2005-01-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
The reaction of the potassium salt of 3-phenyl-5(Z)-(pyridin-2-ylmethylene)-2-thioxoimidazolidin-4-one (KL) with CoCl2·6H2O in MeCN results in formation of the neutral complex CoIIL2. According to single-crystal X-ray analysis, the CoII centre is coordinated to four nitrogen atoms of two organic ligands and has a distorted tetrahedral geometry. This complex undergoes electrochemical reduction with consequent two reversible and one quasi-reversible stages.
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Majouga A. G. et al. The first example of a reversibly reducible CoII complex with an anionic 2-thiohydantoin-type ligand // Mendeleev Communications. 2005. Vol. 15. No. 2. pp. 48-50.
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Majouga A. G., Beloglazkina E. K., Vatsadze S. Z., Moiseeva A. A., Moiseev F. S., Butin K. P., Zyk N. V. The first example of a reversibly reducible CoII complex with an anionic 2-thiohydantoin-type ligand // Mendeleev Communications. 2005. Vol. 15. No. 2. pp. 48-50.
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RIS
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TY - JOUR
DO - 10.1070/MC2005v015n02ABEH002089
UR - https://linkinghub.elsevier.com/retrieve/pii/S0959943605701784
TI - The first example of a reversibly reducible CoII complex with an anionic 2-thiohydantoin-type ligand
T2 - Mendeleev Communications
AU - Majouga, Alexander G.
AU - Beloglazkina, Elena K.
AU - Vatsadze, Sergey Z.
AU - Moiseeva, Anna A.
AU - Moiseev, Fedor S
AU - Butin, Kim P.
AU - Zyk, Nikolai V.
PY - 2005
DA - 2005/01/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 48-50
IS - 2
VL - 15
SN - 0959-9436
SN - 1364-551X
ER -
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BibTex (up to 50 authors)
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@article{2005_Majouga,
author = {Alexander G. Majouga and Elena K. Beloglazkina and Sergey Z. Vatsadze and Anna A. Moiseeva and Fedor S Moiseev and Kim P. Butin and Nikolai V. Zyk},
title = {The first example of a reversibly reducible CoII complex with an anionic 2-thiohydantoin-type ligand},
journal = {Mendeleev Communications},
year = {2005},
volume = {15},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {jan},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0959943605701784},
number = {2},
pages = {48--50},
doi = {10.1070/MC2005v015n02ABEH002089}
}
Cite this
MLA
Copy
Majouga, Alexander G., et al. “The first example of a reversibly reducible CoII complex with an anionic 2-thiohydantoin-type ligand.” Mendeleev Communications, vol. 15, no. 2, Jan. 2005, pp. 48-50. https://linkinghub.elsevier.com/retrieve/pii/S0959943605701784.