Open Access
Catalytic decomposition of diazomethane as a general method for the methylenation of chemical compounds
Publication type: Journal Article
Publication date: 1993-09-30
scimago Q1
wos Q1
SJR: 0.811
CiteScore: 12.9
Impact factor: 6.0
ISSN: 0036021X, 14684837
General Chemistry
Abstract
The principal advances and trends in the application of diazomethane as a methylenating agent in synthetic chemistry using transition and non-transition metal compounds as catalysts are surveyed and analysed. The catalytic reactions of diazomethane with olefins, acethylenes, aromatic compounds, ketones, alcohols and amines are examined. A systematic account is given of data concerning the influence of the structure of the initial substrates and of the nature of the catalyst components on the regio- and stereo-selectivity of the reactions considered. The possibilities of the catalytic conversion by diazomethane (generated in situ) of unsaturated compounds into cyclopropane derivatives are considered. The bibliography includes 284 references.
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Metrics
65
Total citations:
65
Citations from 2024:
4
(6%)
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MLA
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GOST
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Tomilov Y. V. et al. Catalytic decomposition of diazomethane as a general method for the methylenation of chemical compounds // Russian Chemical Reviews. 1993. Vol. 62. No. 9. pp. 799-838.
GOST all authors (up to 50)
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Tomilov Y. V., Dokitchev V. A., Dzhemilev U. M., Nefedov O. M. Catalytic decomposition of diazomethane as a general method for the methylenation of chemical compounds // Russian Chemical Reviews. 1993. Vol. 62. No. 9. pp. 799-838.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1070/RC1993v062n09ABEH000048
UR - https://doi.org/10.1070/RC1993v062n09ABEH000048
TI - Catalytic decomposition of diazomethane as a general method for the methylenation of chemical compounds
T2 - Russian Chemical Reviews
AU - Tomilov, Yury V
AU - Dokitchev, V A
AU - Dzhemilev, Usein M.
AU - Nefedov, Oleg M
PY - 1993
DA - 1993/09/30
PB - Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
SP - 799-838
IS - 9
VL - 62
SN - 0036-021X
SN - 1468-4837
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1993_Tomilov,
author = {Yury V Tomilov and V A Dokitchev and Usein M. Dzhemilev and Oleg M Nefedov},
title = {Catalytic decomposition of diazomethane as a general method for the methylenation of chemical compounds},
journal = {Russian Chemical Reviews},
year = {1993},
volume = {62},
publisher = {Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii},
month = {sep},
url = {https://doi.org/10.1070/RC1993v062n09ABEH000048},
number = {9},
pages = {799--838},
doi = {10.1070/RC1993v062n09ABEH000048}
}
Cite this
MLA
Copy
Tomilov, Yury V., et al. “Catalytic decomposition of diazomethane as a general method for the methylenation of chemical compounds.” Russian Chemical Reviews, vol. 62, no. 9, Sep. 1993, pp. 799-838. https://doi.org/10.1070/RC1993v062n09ABEH000048.