Open Access
Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part I
Publication type: Journal Article
Publication date: 2020-02-01
scimago Q1
wos Q1
SJR: 0.811
CiteScore: 12.9
Impact factor: 6.0
ISSN: 0036021X, 14684837
DOI:
10.1070/RCR4916
General Chemistry
Abstract
The review presents state-of-the-art data on the influence of catalysts (mainly transition metal complexes) on the regioselectivity of a number of reactions. The most important addition reactions to unsaturated bonds are considered, in particular, hydroformylation, hydrosilylation, hydroboration and hydroxy-, alkoxy- and aminocarbonylation, which give predominantly one product. Particular attention is given to reactions with divergent regioselectivity. The reaction conditions, the structures of metal complexes and the ligands involved are indicated and, in some cases, the reaction mechanism is discussed. Examples of industrial processes using homogeneous catalysis are given.
The bibliography includes 203 references.
Dedicated to the memory of V.V.Markovnikov.
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31
Total citations:
31
Citations from 2024:
9
(29%)
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Beletskaya I. P., Nájera C., Yus M. Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part I // Russian Chemical Reviews. 2020. Vol. 89. No. 2. pp. 250-274.
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Beletskaya I. P., Nájera C., Yus M. Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part I // Russian Chemical Reviews. 2020. Vol. 89. No. 2. pp. 250-274.
Cite this
RIS
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TY - JOUR
DO - 10.1070/RCR4916
UR - https://doi.org/10.1070/RCR4916
TI - Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part I
T2 - Russian Chemical Reviews
AU - Beletskaya, Irina P.
AU - Nájera, Carmen
AU - Yus, Miguel
PY - 2020
DA - 2020/02/01
PB - Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
SP - 250-274
IS - 2
VL - 89
SN - 0036-021X
SN - 1468-4837
ER -
Cite this
BibTex (up to 50 authors)
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@article{2020_Beletskaya,
author = {Irina P. Beletskaya and Carmen Nájera and Miguel Yus},
title = {Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part I},
journal = {Russian Chemical Reviews},
year = {2020},
volume = {89},
publisher = {Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii},
month = {feb},
url = {https://doi.org/10.1070/RCR4916},
number = {2},
pages = {250--274},
doi = {10.1070/RCR4916}
}
Cite this
MLA
Copy
Beletskaya, Irina P., et al. “Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part I.” Russian Chemical Reviews, vol. 89, no. 2, Feb. 2020, pp. 250-274. https://doi.org/10.1070/RCR4916.
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