Open Access
Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part I
Тип публикации: Journal Article
Дата публикации: 2020-02-01
scimago Q1
wos Q1
БС1
SJR: 0.811
CiteScore: 12.9
Impact factor: 6.0
ISSN: 0036021X, 14684837
General Chemistry
Краткое описание
The review presents state-of-the-art data on the influence of catalysts (mainly transition metal complexes) on the regioselectivity of a number of reactions. The most important addition reactions to unsaturated bonds are considered, in particular, hydroformylation, hydrosilylation, hydroboration and hydroxy-, alkoxy- and aminocarbonylation, which give predominantly one product. Particular attention is given to reactions with divergent regioselectivity. The reaction conditions, the structures of metal complexes and the ligands involved are indicated and, in some cases, the reaction mechanism is discussed. Examples of industrial processes using homogeneous catalysis are given.
The bibliography includes 203 references.
Dedicated to the memory of V.V.Markovnikov.
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Beletskaya I. P., Nájera C., Yus M. Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part I // Russian Chemical Reviews. 2020. Vol. 89. No. 2. pp. 250-274.
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Beletskaya I. P., Nájera C., Yus M. Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part I // Russian Chemical Reviews. 2020. Vol. 89. No. 2. pp. 250-274.
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TY - JOUR
DO - 10.1070/RCR4916
UR - https://doi.org/10.1070/RCR4916
TI - Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part I
T2 - Russian Chemical Reviews
AU - Beletskaya, Irina P.
AU - Nájera, Carmen
AU - Yus, Miguel
PY - 2020
DA - 2020/02/01
PB - Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
SP - 250-274
IS - 2
VL - 89
SN - 0036-021X
SN - 1468-4837
ER -
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@article{2020_Beletskaya,
author = {Irina P. Beletskaya and Carmen Nájera and Miguel Yus},
title = {Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part I},
journal = {Russian Chemical Reviews},
year = {2020},
volume = {89},
publisher = {Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii},
month = {feb},
url = {https://doi.org/10.1070/RCR4916},
number = {2},
pages = {250--274},
doi = {10.1070/RCR4916}
}
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Beletskaya, Irina P., et al. “Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part I.” Russian Chemical Reviews, vol. 89, no. 2, Feb. 2020, pp. 250-274. https://doi.org/10.1070/RCR4916.