Open Access
Organofluorine chemistry: promising growth areas and challenges
Larisa V Politanskaya
,
Galina A. Selivanova
,
Elena V Panteleeva
,
Vyacheslav E Platonov
,
Pavel V Nikulshin
,
Andrey S Vinogradov
,
Yaroslav V Zonov
,
Victor M Karpov
,
Tatyana V Mezhenkova
,
Aleksander V Vasilyev
,
Andrei B. Koldobskii
,
Olga S Shilova
,
Yanina V. Burgart
,
Victor I. Saloutin
,
Vladimir B Sokolov
,
Aleksey Yu Aksinenko
,
Valentine G Nenajdenko
,
Mikhail Yu Moskalik
,
Vera V Astakhova
,
Bagrat A. Shainyan
,
Andrey A Tabolin
,
Sema L Ioffe
,
Vasiliy M Muzalevskiy
,
Elizaveta S. Balenkova
,
Alexey V. Shastin
,
Andrey A Tyutyunov
,
Vladimir E. Boiko
,
Sergei M Igumnov
,
Nicolay Yu Adonin
,
Vadim V Bardin
,
Salekh M Masoud
,
Daria V Vorobyeva
,
Emiliya V. Nosova
,
Galina N. Lipunova
,
Valery N. Charushin
,
Arkady G Makarov
,
Andrey V Zibarev
,
Boris A. Trofimov
,
Lyubov N. Sobenina
,
Kseniya V Belyaeva
,
Dmitrii L Obydennov
,
Sergey A Usachev
Publication type: Journal Article
Publication date: 2019-05-01
scimago Q1
wos Q1
SJR: 0.811
CiteScore: 12.9
Impact factor: 6.0
ISSN: 0036021X, 14684837
DOI:
10.1070/RCR4871
General Chemistry
Abstract
Currently, the chemistry of organofluorine compounds is a leading and rapidly developing area of organic chemistry. Fluorine present in a molecule largely determines its specific chemical and biological properties. This thematic issue covers the trends of organofluorine chemistry that have been actively developed in Russia the last 15 – 20 years. The review describes nucleophilic substitution and heterocyclization reactions involving fluorinated arenes and quinones and skeletal cationoid rearrangements in the polyfluoroarene series. The transformations involving CF3-substituted carbocations and radical cations are considered. Heterocyclization and oxidative addition reactions of trifluoroacetamide derivatives and transformations of the organic moiety in polyfluorinated organoboranes and borates with retention of the carbon – boron bond are discussed. Particular attention is devoted to catalytic olefination using freons as an efficient synthetic route to fluorinated compounds. The application of unsymmetrical fluorine-containing N-heterocyclic carbene ligands as catalysts for olefin metathesis is demonstrated. A variety of classes of organofluorine compounds are considered, in particular, polyfluorinated arenes and 1,2-diaminobenzenes, 1-halo-2-trifluoroacetylacetylenes, α-fluoronitro compounds, fluorinated heterocycles, 2-hydrazinylidene-1,3-dicarbonyl derivatives, imines and silanes. The potential practical applications of organofluorine compounds in fundamental organic chemistry, materials science and biomedicine are outlined.
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162
Total citations:
162
Citations from 2024:
38
(23.46%)
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GOST
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Politanskaya L. V. et al. Organofluorine chemistry: promising growth areas and challenges // Russian Chemical Reviews. 2019. Vol. 88. No. 5. pp. 425-569.
GOST all authors (up to 50)
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Politanskaya L. V., Selivanova G. A., Panteleeva E. V., Tretyakov E. V., Platonov V. E., Nikulshin P. V., Vinogradov A. S., Zonov Y. V., Karpov V. M., Mezhenkova T. V., Vasilyev A. V., Koldobskii A. B., Shilova O. S., Morozova S. M., Burgart Y. V., Shchegolkov E. V., Saloutin V. I., Sokolov V. B., Aksinenko A. Yu., Nenajdenko V. G., Moskalik M. Yu., Astakhova V. V., Shainyan B. A., Tabolin A. A., Ioffe S. L., Muzalevskiy V. M., Balenkova E. S., Shastin A. V., Tyutyunov A. A., Boiko V. E., Igumnov S. M., Dilman A. D., Adonin N. Yu., Bardin V. V., Masoud S. M., Vorobyeva D. V., Osipov S. N., Nosova E. V., Lipunova G. N., Charushin V. N., Prima D. O., Makarov A. G., Zibarev A. V., Trofimov B. A., Sobenina L. N., Belyaeva K. V., Sosnovskikh V. Ya., Obydennov D. L., Usachev S. A. Organofluorine chemistry: promising growth areas and challenges // Russian Chemical Reviews. 2019. Vol. 88. No. 5. pp. 425-569.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1070/RCR4871
UR - https://doi.org/10.1070/RCR4871
TI - Organofluorine chemistry: promising growth areas and challenges
T2 - Russian Chemical Reviews
AU - Politanskaya, Larisa V
AU - Selivanova, Galina A.
AU - Panteleeva, Elena V
AU - Tretyakov, Evgeny V
AU - Platonov, Vyacheslav E
AU - Nikulshin, Pavel V
AU - Vinogradov, Andrey S
AU - Zonov, Yaroslav V
AU - Karpov, Victor M
AU - Mezhenkova, Tatyana V
AU - Vasilyev, Aleksander V
AU - Koldobskii, Andrei B.
AU - Shilova, Olga S
AU - Morozova, Sofia M.
AU - Burgart, Yanina V.
AU - Shchegolkov, Evgeny V
AU - Saloutin, Victor I.
AU - Sokolov, Vladimir B
AU - Aksinenko, Aleksey Yu
AU - Nenajdenko, Valentine G
AU - Moskalik, Mikhail Yu
AU - Astakhova, Vera V
AU - Shainyan, Bagrat A.
AU - Tabolin, Andrey A
AU - Ioffe, Sema L
AU - Muzalevskiy, Vasiliy M
AU - Balenkova, Elizaveta S.
AU - Shastin, Alexey V.
AU - Tyutyunov, Andrey A
AU - Boiko, Vladimir E.
AU - Igumnov, Sergei M
AU - Dilman, Alexander D
AU - Adonin, Nicolay Yu
AU - Bardin, Vadim V
AU - Masoud, Salekh M
AU - Vorobyeva, Daria V
AU - Osipov, Sergey N
AU - Nosova, Emiliya V.
AU - Lipunova, Galina N.
AU - Charushin, Valery N.
AU - Prima, Darya O
AU - Makarov, Arkady G
AU - Zibarev, Andrey V
AU - Trofimov, Boris A.
AU - Sobenina, Lyubov N.
AU - Belyaeva, Kseniya V
AU - Sosnovskikh, Vyacheslav Ya
AU - Obydennov, Dmitrii L
AU - Usachev, Sergey A
PY - 2019
DA - 2019/05/01
PB - Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
SP - 425-569
IS - 5
VL - 88
SN - 0036-021X
SN - 1468-4837
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Politanskaya,
author = {Larisa V Politanskaya and Galina A. Selivanova and Elena V Panteleeva and Evgeny V Tretyakov and Vyacheslav E Platonov and Pavel V Nikulshin and Andrey S Vinogradov and Yaroslav V Zonov and Victor M Karpov and Tatyana V Mezhenkova and Aleksander V Vasilyev and Andrei B. Koldobskii and Olga S Shilova and Sofia M. Morozova and Yanina V. Burgart and Evgeny V Shchegolkov and Victor I. Saloutin and Vladimir B Sokolov and Aleksey Yu Aksinenko and Valentine G Nenajdenko and Mikhail Yu Moskalik and Vera V Astakhova and Bagrat A. Shainyan and Andrey A Tabolin and Sema L Ioffe and Vasiliy M Muzalevskiy and Elizaveta S. Balenkova and Alexey V. Shastin and Andrey A Tyutyunov and Vladimir E. Boiko and Sergei M Igumnov and Alexander D Dilman and Nicolay Yu Adonin and Vadim V Bardin and Salekh M Masoud and Daria V Vorobyeva and Sergey N Osipov and Emiliya V. Nosova and Galina N. Lipunova and Valery N. Charushin and Darya O Prima and Arkady G Makarov and Andrey V Zibarev and Boris A. Trofimov and Lyubov N. Sobenina and Kseniya V Belyaeva and Vyacheslav Ya Sosnovskikh and Dmitrii L Obydennov and Sergey A Usachev},
title = {Organofluorine chemistry: promising growth areas and challenges},
journal = {Russian Chemical Reviews},
year = {2019},
volume = {88},
publisher = {Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii},
month = {may},
url = {https://doi.org/10.1070/RCR4871},
number = {5},
pages = {425--569},
doi = {10.1070/RCR4871}
}
Cite this
MLA
Copy
Politanskaya, Larisa V., et al. “Organofluorine chemistry: promising growth areas and challenges.” Russian Chemical Reviews, vol. 88, no. 5, May. 2019, pp. 425-569. https://doi.org/10.1070/RCR4871.