Australian Journal of Chemistry, volume 66, issue 3, pages 286
1,5-(1,7)-Biradicals and Nitrenes Formed by Ring Opening of Hetarylnitrenes
Publication type: Journal Article
Publication date: 2013-02-11
Journal:
Australian Journal of Chemistry
Quartile SCImago
Q3
Quartile WOS
Q4
SJR: 0.267
CiteScore: 2.5
Impact factor: 1
ISSN: 00049425, 14450038
DOI:
10.1071/CH12502
General Chemistry
Abstract
Several aromatic and heteroaromatic nitrenes and carbenes undergo photochemical and sometimes also thermal ring opening. Depending on benz-annelation, the ring-opened species may have the character of either nitrenes (for α-annelation) or 1,5-(1,7-)-biradicals (for β-annelation). Both types have been observed, and they are clearly distinguished by their characteristic electron spin resonance spectra. In addition, ring opening of hetarylnitrenes to nitrile ylides can be observed whenever there is a meta-relationship between a ring nitrogen atom and the nitrene (or carbene) centre. The factors governing the two types of ring opening have been investigated. The nitrenes and carbenes are generated by either low temperature Ar matrix photolysis or flash vacuum thermolysis of azides, tetrazoles, triazoles, or diazo compounds with matrix isolation of the products.
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Wentrup C., Kvaskoff D. 1,5-(1,7)-Biradicals and Nitrenes Formed by Ring Opening of Hetarylnitrenes // Australian Journal of Chemistry. 2013. Vol. 66. No. 3. p. 286.
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Wentrup C., Kvaskoff D. 1,5-(1,7)-Biradicals and Nitrenes Formed by Ring Opening of Hetarylnitrenes // Australian Journal of Chemistry. 2013. Vol. 66. No. 3. p. 286.
Cite this
RIS
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TY - JOUR
DO - 10.1071/CH12502
UR - https://doi.org/10.1071/CH12502
TI - 1,5-(1,7)-Biradicals and Nitrenes Formed by Ring Opening of Hetarylnitrenes
T2 - Australian Journal of Chemistry
AU - Wentrup, Curt
AU - Kvaskoff, David
PY - 2013
DA - 2013/02/11
PB - CSIRO Publishing
SP - 286
IS - 3
VL - 66
SN - 0004-9425
SN - 1445-0038
ER -
Cite this
BibTex
Copy
@article{2013_Wentrup,
author = {Curt Wentrup and David Kvaskoff},
title = {1,5-(1,7)-Biradicals and Nitrenes Formed by Ring Opening of Hetarylnitrenes},
journal = {Australian Journal of Chemistry},
year = {2013},
volume = {66},
publisher = {CSIRO Publishing},
month = {feb},
url = {https://doi.org/10.1071/CH12502},
number = {3},
pages = {286},
doi = {10.1071/CH12502}
}
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MLA
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Wentrup, Curt, and David Kvaskoff. “1,5-(1,7)-Biradicals and Nitrenes Formed by Ring Opening of Hetarylnitrenes.” Australian Journal of Chemistry, vol. 66, no. 3, Feb. 2013, p. 286. https://doi.org/10.1071/CH12502.