Monometallic Ln3+and heterometallic Ln3+-Cd2+complexes based on pentafluorophenylacetic acid: Efficient control of dimension and luminescent properties
Тип публикации: Journal Article
Дата публикации: 2022-02-14
scimago Q3
wos Q4
БС3
SJR: 0.279
CiteScore: 2.6
Impact factor: 0.9
ISSN: 00049425, 14450038
General Chemistry
Краткое описание
Four new complexes [Ln(pfaa)3(H2O)2]n (Ln = Eu (1), Tb (2)) and [Ln2Cd2(pfaa)10 (phen)2(EtOH)2]·2MeCN (Ln = Eu (3), Tb (4), phen = 1,10-phenanthroline) based on pentaphorphenylacetic acid (Hpfaa) have been prepared and completely investigated. The structures of compounds 1 and 3 were studied by single crystal X-ray diffraction analysis: the isostructural complexes 1 and 2 represent 1D coordination polymer, while the isostructural complexes 3 and 4 are molecular compounds. Complexes 1–4 show strong lanthanide-centred luminescence, since the introduction of phenanthroline leads to a significant increase in the observed lifetime (τobs) and photoluminescent quantum yield.
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Belousov Y. A. et al. Monometallic Ln3+and heterometallic Ln3+-Cd2+complexes based on pentafluorophenylacetic acid: Efficient control of dimension and luminescent properties // Australian Journal of Chemistry. 2022. Vol. 75. No. 9. pp. 572-580.
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Belousov Y. A., Kiskin M. A., Sidoruk A. V., Varaksina E. A., Shmelev M. A., Gogoleva N. V., Taydakov I. V., Eremenko I. L. Monometallic Ln3+and heterometallic Ln3+-Cd2+complexes based on pentafluorophenylacetic acid: Efficient control of dimension and luminescent properties // Australian Journal of Chemistry. 2022. Vol. 75. No. 9. pp. 572-580.
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TY - JOUR
DO - 10.1071/CH21333
UR - https://doi.org/10.1071/CH21333
TI - Monometallic Ln3+and heterometallic Ln3+-Cd2+complexes based on pentafluorophenylacetic acid: Efficient control of dimension and luminescent properties
T2 - Australian Journal of Chemistry
AU - Belousov, Yury A.
AU - Kiskin, Mikhail A.
AU - Sidoruk, A. V.
AU - Varaksina, E. A.
AU - Shmelev, M. A.
AU - Gogoleva, N. V.
AU - Taydakov, Ilya V.
AU - Eremenko, Igor L.
PY - 2022
DA - 2022/02/14
PB - CSIRO Publishing
SP - 572-580
IS - 9
VL - 75
SN - 0004-9425
SN - 1445-0038
ER -
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@article{2022_Belousov,
author = {Yury A. Belousov and Mikhail A. Kiskin and A. V. Sidoruk and E. A. Varaksina and M. A. Shmelev and N. V. Gogoleva and Ilya V. Taydakov and Igor L. Eremenko},
title = {Monometallic Ln3+and heterometallic Ln3+-Cd2+complexes based on pentafluorophenylacetic acid: Efficient control of dimension and luminescent properties},
journal = {Australian Journal of Chemistry},
year = {2022},
volume = {75},
publisher = {CSIRO Publishing},
month = {feb},
url = {https://doi.org/10.1071/CH21333},
number = {9},
pages = {572--580},
doi = {10.1071/CH21333}
}
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Belousov, Yury A., et al. “Monometallic Ln3+and heterometallic Ln3+-Cd2+complexes based on pentafluorophenylacetic acid: Efficient control of dimension and luminescent properties.” Australian Journal of Chemistry, vol. 75, no. 9, Feb. 2022, pp. 572-580. https://doi.org/10.1071/CH21333.