Monometallic Ln3+and heterometallic Ln3+-Cd2+complexes based on pentafluorophenylacetic acid: Efficient control of dimension and luminescent properties
Yury A. Belousov
1, 2
,
A. V. Sidoruk
1
,
E. A. Varaksina
2
,
M. A. Shmelev
3
,
N. V. Gogoleva
3
,
Ilya V. Taydakov
2, 4
,
Publication type: Journal Article
Publication date: 2022-02-14
scimago Q3
wos Q4
SJR: 0.279
CiteScore: 2.6
Impact factor: 0.9
ISSN: 00049425, 14450038
DOI:
10.1071/CH21333
General Chemistry
Abstract
Four new complexes [Ln(pfaa)3(H2O)2]n (Ln = Eu (1), Tb (2)) and [Ln2Cd2(pfaa)10 (phen)2(EtOH)2]·2MeCN (Ln = Eu (3), Tb (4), phen = 1,10-phenanthroline) based on pentaphorphenylacetic acid (Hpfaa) have been prepared and completely investigated. The structures of compounds 1 and 3 were studied by single crystal X-ray diffraction analysis: the isostructural complexes 1 and 2 represent 1D coordination polymer, while the isostructural complexes 3 and 4 are molecular compounds. Complexes 1–4 show strong lanthanide-centred luminescence, since the introduction of phenanthroline leads to a significant increase in the observed lifetime (τobs) and photoluminescent quantum yield.
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Total citations:
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Citations from 2024:
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(45.45%)
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GOST
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Belousov Y. A. et al. Monometallic Ln3+and heterometallic Ln3+-Cd2+complexes based on pentafluorophenylacetic acid: Efficient control of dimension and luminescent properties // Australian Journal of Chemistry. 2022. Vol. 75. No. 9. pp. 572-580.
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Belousov Y. A., Kiskin M. A., Sidoruk A. V., Varaksina E. A., Shmelev M. A., Gogoleva N. V., Taydakov I. V., Eremenko I. L. Monometallic Ln3+and heterometallic Ln3+-Cd2+complexes based on pentafluorophenylacetic acid: Efficient control of dimension and luminescent properties // Australian Journal of Chemistry. 2022. Vol. 75. No. 9. pp. 572-580.
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RIS
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TY - JOUR
DO - 10.1071/CH21333
UR - https://doi.org/10.1071/CH21333
TI - Monometallic Ln3+and heterometallic Ln3+-Cd2+complexes based on pentafluorophenylacetic acid: Efficient control of dimension and luminescent properties
T2 - Australian Journal of Chemistry
AU - Belousov, Yury A.
AU - Kiskin, Mikhail A.
AU - Sidoruk, A. V.
AU - Varaksina, E. A.
AU - Shmelev, M. A.
AU - Gogoleva, N. V.
AU - Taydakov, Ilya V.
AU - Eremenko, Igor L.
PY - 2022
DA - 2022/02/14
PB - CSIRO Publishing
SP - 572-580
IS - 9
VL - 75
SN - 0004-9425
SN - 1445-0038
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2022_Belousov,
author = {Yury A. Belousov and Mikhail A. Kiskin and A. V. Sidoruk and E. A. Varaksina and M. A. Shmelev and N. V. Gogoleva and Ilya V. Taydakov and Igor L. Eremenko},
title = {Monometallic Ln3+and heterometallic Ln3+-Cd2+complexes based on pentafluorophenylacetic acid: Efficient control of dimension and luminescent properties},
journal = {Australian Journal of Chemistry},
year = {2022},
volume = {75},
publisher = {CSIRO Publishing},
month = {feb},
url = {https://doi.org/10.1071/CH21333},
number = {9},
pages = {572--580},
doi = {10.1071/CH21333}
}
Cite this
MLA
Copy
Belousov, Yury A., et al. “Monometallic Ln3+and heterometallic Ln3+-Cd2+complexes based on pentafluorophenylacetic acid: Efficient control of dimension and luminescent properties.” Australian Journal of Chemistry, vol. 75, no. 9, Feb. 2022, pp. 572-580. https://doi.org/10.1071/CH21333.