Open Access

Proceedings of the National Academy of Sciences (PNAS)

Proceedings of the National Academy of Sciences of the United States of America

, volume 116 , issue 38 , pages 18815-18821

High-performance all-solid-state batteries enabled by salt bonding to perovskite in poly(ethylene oxide)

Henghui Xu ^{1, 2}

Po‐Hsiu Chien ^{3, 4}

Jianjian Shi ^{1, 2}

Yutao Li ^{1, 2}

Nan Wu ^{1, 2}

Yuanyue Liu ^{1, 2}

Yan-Yan Hu ^{3, 4}

John Goodenough ^{1, 2}

Hide authors affiliations Show authors affiliations: 4 affiliations

Materials Science and Engineering Program, The University of Texas at Austin, Austin, TX 78712; |

Texas Materials Institute, The University of Texas at Austin, Austin, TX 78712; |

Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306; |

⁴

Center of Interdisciplinary Magnetic Resonance, National High Magnetic Field Laboratory, Tallahassee, FL 32310 |

Publication type: Journal Article

Publication date: 2019-08-29

Proceedings of the National Academy of Sciences (PNAS)

Proceedings of the National Academy of Sciences of the United States of America

scimago Q1

wos Q1

SJR: 3.414

CiteScore: 16.5

Impact factor: 9.1

ISSN: 00278424, 10916490

DOI: 10.1073/pnas.1907507116

Copy DOI

PubMed ID: 31467166

Multidisciplinary

Abstract

Significance

Use of a flexible solid polymer electrolyte is a common strategy to obtain an all-solid-state lithium battery of high stored electric power at acceptable charge–discharge cycling rates. Commercial realization of this strategy with poly(ethylene oxide) containing a garnet ceramic has been unsuccessful and dendrites form and grow across garnet electrolytes without proper treatment of the garnet surface. We report that use of a perovskite Li ⁺ electrolyte in place of the garnet ceramic provides an adequate Li ⁺ conductivity at 25 °C without dendrite formation. We also demonstrate a binding of the TFSI ⁻ anion of a LiTFSI [lithium bis(trifluoromethanesulfonyl)imide] salt to the polymer, which increases both the Li ⁺ conductivity and the Li ⁺ transport number.

Found

1 citation

Voropaeva Daria

PhD in Chemistry

33 publications, 507 citations, 18 reviews

h-index: 13

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Research interests

Green technologies

Lithium-ion batteries

Membrane materials

Sodium-ion batteries

1 citation

Chun-Chen Yang

293 publications, 9 036 citations, 72 reviews

h-index: 52

Ming Chi University of Technology

Chang Gung University

Chang Gung University of Science and Technology

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260

Cite this

GOST |

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GOST Copy

Xu H. et al. High-performance all-solid-state batteries enabled by salt bonding to perovskite in poly(ethylene oxide) // Proceedings of the National Academy of Sciences of the United States of America. 2019. Vol. 116. No. 38. pp. 18815-18821.

GOST all authors (up to 50) Copy

Xu H., Chien P., Shi J., Li Y., Wu N., Liu Y., Hu Y., Goodenough J. High-performance all-solid-state batteries enabled by salt bonding to perovskite in poly(ethylene oxide) // Proceedings of the National Academy of Sciences of the United States of America. 2019. Vol. 116. No. 38. pp. 18815-18821.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1073/pnas.1907507116

UR - https://doi.org/10.1073/pnas.1907507116

TI - High-performance all-solid-state batteries enabled by salt bonding to perovskite in poly(ethylene oxide)

T2 - Proceedings of the National Academy of Sciences of the United States of America

AU - Xu, Henghui

AU - Chien, Po‐Hsiu

AU - Shi, Jianjian

AU - Li, Yutao

AU - Wu, Nan

AU - Liu, Yuanyue

AU - Hu, Yan-Yan

AU - Goodenough, John

PY - 2019

DA - 2019/08/29

PB - Proceedings of the National Academy of Sciences (PNAS)

SP - 18815-18821

IS - 38

VL - 116

PMID - 31467166

SN - 0027-8424

SN - 1091-6490

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2019_Xu,

author = {Henghui Xu and Po‐Hsiu Chien and Jianjian Shi and Yutao Li and Nan Wu and Yuanyue Liu and Yan-Yan Hu and John Goodenough},

title = {High-performance all-solid-state batteries enabled by salt bonding to perovskite in poly(ethylene oxide)},

journal = {Proceedings of the National Academy of Sciences of the United States of America},

year = {2019},

volume = {116},

publisher = {Proceedings of the National Academy of Sciences (PNAS)},

month = {aug},

url = {https://doi.org/10.1073/pnas.1907507116},

number = {38},

pages = {18815--18821},

doi = {10.1073/pnas.1907507116}

}

MLA

Cite this

MLA Copy

Xu, Henghui, et al. “High-performance all-solid-state batteries enabled by salt bonding to perovskite in poly(ethylene oxide).” Proceedings of the National Academy of Sciences of the United States of America, vol. 116, no. 38, Aug. 2019, pp. 18815-18821. https://doi.org/10.1073/pnas.1907507116.

Publisher

Proceedings of the National Academy of Sciences (PNAS)

Journal

Proceedings of the National Academy of Sciences of the United States of America

scimago Q1

wos Q1

SJR

3.414

CiteScore

16.5

Impact factor

9.1

ISSN

00278424 (Print)

10916490 (Electronic)