Direct electrochemical synthesis of metal complexes of phthalocyanines and azomethines as model compounds: Advantages and problems of this method versus traditional synthetic techniques
Boris I. Kharisov
1
,
Alexander D Garnovskii
2, 3
,
Oxana V. Kharissova
1
,
Ubaldo Ortiz Méndez
1, 4
,
Aslan Yu. Tsivadze
5, 6
Publication type: Journal Article
Publication date: 2007-07-01
scimago Q3
wos Q3
SJR: 0.294
CiteScore: 3.4
Impact factor: 2.1
ISSN: 00958972, 10290389
Materials Chemistry
Physical and Theoretical Chemistry
Abstract
A comparison of traditional and electrochemical synthetic techniques for obtaining metal complexes of azomethine and phthalocyanine is reported. It is shown that the electrochemical method affords azomethinic coordination compounds free of anions of precursors and with higher yields at ambient temperature. Electrolysis in a solid phase of phthalonitrile using a high-surface platinum cathode leads to metal-free phthalocyanine and metal phthalocyaninates at 0–25°C. The typical problems of the electrosynthetic procedures in different conditions are discussed in detail.
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19
Total citations:
19
Citations from 2024:
2
(10%)
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GOST
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Kharisov B. I. et al. Direct electrochemical synthesis of metal complexes of phthalocyanines and azomethines as model compounds: Advantages and problems of this method versus traditional synthetic techniques // Journal of Coordination Chemistry. 2007. Vol. 60. No. 13. pp. 1435-1455.
GOST all authors (up to 50)
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Kharisov B. I., Garnovskii A. D., Kharissova O. V., Méndez U. O., Tsivadze A. Y. Direct electrochemical synthesis of metal complexes of phthalocyanines and azomethines as model compounds: Advantages and problems of this method versus traditional synthetic techniques // Journal of Coordination Chemistry. 2007. Vol. 60. No. 13. pp. 1435-1455.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1080/00958970601040658
UR - https://www.tandfonline.com/doi/full/10.1080/00958970601040658
TI - Direct electrochemical synthesis of metal complexes of phthalocyanines and azomethines as model compounds: Advantages and problems of this method versus traditional synthetic techniques
T2 - Journal of Coordination Chemistry
AU - Kharisov, Boris I.
AU - Garnovskii, Alexander D
AU - Kharissova, Oxana V.
AU - Méndez, Ubaldo Ortiz
AU - Tsivadze, Aslan Yu.
PY - 2007
DA - 2007/07/01
PB - Taylor & Francis
SP - 1435-1455
IS - 13
VL - 60
SN - 0095-8972
SN - 1029-0389
ER -
Cite this
BibTex (up to 50 authors)
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@article{2007_Kharisov,
author = {Boris I. Kharisov and Alexander D Garnovskii and Oxana V. Kharissova and Ubaldo Ortiz Méndez and Aslan Yu. Tsivadze},
title = {Direct electrochemical synthesis of metal complexes of phthalocyanines and azomethines as model compounds: Advantages and problems of this method versus traditional synthetic techniques},
journal = {Journal of Coordination Chemistry},
year = {2007},
volume = {60},
publisher = {Taylor & Francis},
month = {jul},
url = {https://www.tandfonline.com/doi/full/10.1080/00958970601040658},
number = {13},
pages = {1435--1455},
doi = {10.1080/00958970601040658}
}
Cite this
MLA
Copy
Kharisov, Boris I., et al. “Direct electrochemical synthesis of metal complexes of phthalocyanines and azomethines as model compounds: Advantages and problems of this method versus traditional synthetic techniques.” Journal of Coordination Chemistry, vol. 60, no. 13, Jul. 2007, pp. 1435-1455. https://www.tandfonline.com/doi/full/10.1080/00958970601040658.
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