volume 48 issue 2 pages 91-144

Selective Hydrogenation of Ethyne in Ethene‐Rich Streams on Palladium Catalysts. Part 1. Effect of Changes to the Catalyst During Reaction

Publication typeJournal Article
Publication date2006-07-01
scimago Q1
wos Q1
SJR2.510
CiteScore23.6
Impact factor10.1
ISSN01614940, 15205703
General Chemistry
Catalysis
Process Chemistry and Technology
Abstract
The effect of various changes to the palladium catalyst during its stabilization in the course of the selective hydrogenation of ethyne‐ethene mixtures (formation of hydride and carbide phases and of carbonaceous deposits) was reviewed. The deposits in the form of a carbonaceous overlayer on the palladium surface create sites at which selective ethyne hydrogenation to ethene can occur. The carbonaceous deposit on the support increases the selectivity to ethane formation by increasing the rate of ethene hydrogenation on support sites (spillover of hydrogen from metal to the support surface) and by decreasing the effective diffusivity of ethyne in the pores.
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Borodziński A., Bond G. C. Selective Hydrogenation of Ethyne in Ethene‐Rich Streams on Palladium Catalysts. Part 1. Effect of Changes to the Catalyst During Reaction // Catalysis Reviews - Science and Engineering. 2006. Vol. 48. No. 2. pp. 91-144.
GOST all authors (up to 50) Copy
Borodziński A., Bond G. C. Selective Hydrogenation of Ethyne in Ethene‐Rich Streams on Palladium Catalysts. Part 1. Effect of Changes to the Catalyst During Reaction // Catalysis Reviews - Science and Engineering. 2006. Vol. 48. No. 2. pp. 91-144.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1080/01614940500364909
UR - https://doi.org/10.1080/01614940500364909
TI - Selective Hydrogenation of Ethyne in Ethene‐Rich Streams on Palladium Catalysts. Part 1. Effect of Changes to the Catalyst During Reaction
T2 - Catalysis Reviews - Science and Engineering
AU - Borodziński, Andrzej
AU - Bond, Geoffrey C
PY - 2006
DA - 2006/07/01
PB - Taylor & Francis
SP - 91-144
IS - 2
VL - 48
SN - 0161-4940
SN - 1520-5703
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2006_Borodziński,
author = {Andrzej Borodziński and Geoffrey C Bond},
title = {Selective Hydrogenation of Ethyne in Ethene‐Rich Streams on Palladium Catalysts. Part 1. Effect of Changes to the Catalyst During Reaction},
journal = {Catalysis Reviews - Science and Engineering},
year = {2006},
volume = {48},
publisher = {Taylor & Francis},
month = {jul},
url = {https://doi.org/10.1080/01614940500364909},
number = {2},
pages = {91--144},
doi = {10.1080/01614940500364909}
}
MLA
Cite this
MLA Copy
Borodziński, Andrzej, and Geoffrey C Bond. “Selective Hydrogenation of Ethyne in Ethene‐Rich Streams on Palladium Catalysts. Part 1. Effect of Changes to the Catalyst During Reaction.” Catalysis Reviews - Science and Engineering, vol. 48, no. 2, Jul. 2006, pp. 91-144. https://doi.org/10.1080/01614940500364909.