Solvent Extraction and Ion Exchange

, том 8 , издание 1 , страницы 187-197

THERMODYNAMICS OF ALKALI AND ALKALINE EARTH METAL ION-EXCHANGE ON ZIRCONIUM SULPHOPHOSPHONATES

Тип публикации: Journal Article

Дата публикации: 1990-03-01

Taylor & Francis

Solvent Extraction and Ion Exchange

SCImago Q3

WOS Q3

БС2

SJR: 0.335

CiteScore: 3.5

Impact factor: 2.1

ISSN: 07366299, 15322262

DOI: 10.1080/07366299008917993

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General Chemistry

General Chemical Engineering

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Abstract The thermodynamics of alkali and alkaline earth metal ion exchange on a layered zirconium sulphophosphonate having the general composition Zr(O3PC6H4SO3H) ×(HPO4) 2−× yH2O have been investigated. Enthalpy and entropy changes accompanying the M2+ - H+ exchange (M = Na+, Cs+, Mg2+ and Ba2+)were determined by the temperature variation method. For the monovalent ions, Na+ and Cs+, the enthalpy terms favor exchange whereas the entropy terms are unfavorable. In contrast, for the divalent ions, Mg2+ and Ba2+, the exchange is due to highly favorable entropy terms.

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ГОСТ |

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Kullberg L. H., Clearfield A. THERMODYNAMICS OF ALKALI AND ALKALINE EARTH METAL ION-EXCHANGE ON ZIRCONIUM SULPHOPHOSPHONATES // Solvent Extraction and Ion Exchange. 1990. Vol. 8. No. 1. pp. 187-197.

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Kullberg L. H., Clearfield A. THERMODYNAMICS OF ALKALI AND ALKALINE EARTH METAL ION-EXCHANGE ON ZIRCONIUM SULPHOPHOSPHONATES // Solvent Extraction and Ion Exchange. 1990. Vol. 8. No. 1. pp. 187-197.

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TY - JOUR

DO - 10.1080/07366299008917993

UR - http://www.tandfonline.com/doi/abs/10.1080/07366299008917993

TI - THERMODYNAMICS OF ALKALI AND ALKALINE EARTH METAL ION-EXCHANGE ON ZIRCONIUM SULPHOPHOSPHONATES

T2 - Solvent Extraction and Ion Exchange

AU - Kullberg, L H

AU - Clearfield, A.

PY - 1990

DA - 1990/03/01

PB - Taylor & Francis

SP - 187-197

IS - 1

VL - 8

SN - 0736-6299

SN - 1532-2262

ER -

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@article{1990_Kullberg,

author = {L H Kullberg and A. Clearfield},

title = {THERMODYNAMICS OF ALKALI AND ALKALINE EARTH METAL ION-EXCHANGE ON ZIRCONIUM SULPHOPHOSPHONATES},

journal = {Solvent Extraction and Ion Exchange},

year = {1990},

volume = {8},

publisher = {Taylor & Francis},

month = {mar},

url = {http://www.tandfonline.com/doi/abs/10.1080/07366299008917993},

number = {1},

pages = {187--197},

doi = {10.1080/07366299008917993}

}

MLA

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Kullberg, L. H., and A. Clearfield. “THERMODYNAMICS OF ALKALI AND ALKALINE EARTH METAL ION-EXCHANGE ON ZIRCONIUM SULPHOPHOSPHONATES.” Solvent Extraction and Ion Exchange, vol. 8, no. 1, Mar. 1990, pp. 187-197. http://www.tandfonline.com/doi/abs/10.1080/07366299008917993.

Издатель

Taylor & Francis

Журнал

Solvent Extraction and Ion Exchange

SCImago Q3

WOS Q3

БС2

SJR

0.335

CiteScore

3.5

Impact factor