Solvent Extraction and Ion Exchange

, том 16 , издание 1 , страницы 151-221

Ion-exchange isothermal supersaturation

Dmitri Muraviev ¹

Ruslan Khamizov ²

Nikolai A Tikhonov ³

Скрыть аффилиации авторов Показать аффилиации авторов: 3 аффилиации

Department of Physical Chemistry, Chemical Faculty , Lomonosov Moscow State University , Moscow, 119899, Russia |

Vemadsky Institute of Geological and Analytical Chemistry , Moscow, Russia |

Department of Mathematics, Physical Faculty , Lomonosov Moscow State University , Moscow, 119899, Russia |

Тип публикации: Journal Article

Дата публикации: 1998-01-01

Taylor & Francis

Solvent Extraction and Ion Exchange

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SJR: 0.365

CiteScore: 4.2

Impact factor: 2.1

ISSN: 07366299, 15322262

DOI: 10.1080/07366299808934529

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General Chemistry

General Chemical Engineering

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The paper describes the new phenomenon called Ion-Exchange Isothermal Supersaturahon (IXISS). This effect is observed for a number of ion-exchange systems, where frontal or reverse frontal separation is accompanied by the formation of stable supersaturated solutions of slightly soluble substances in the interstitial space of ion-exchange columns. After leaving the column a supersaturated solution crystallizes spontaneously, which allows for designing practically ideal ion-exchange process where a crystalline product is obtained right after the ion-exchange purification cycle. The paper comprises results on experimental investigation of IXISS of amino acids (e.g., such as glutamic, aspartic and some others), calcium and magnesium salts (sulfates and carbonates), and some other substances. The mechanisms of stabilization of supersaturated amino acid solutions in the interstitial space is proposed and confirmed experimentally. Methods for identification of substances exhibiting the IXISS effect and ...

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Muraviev D. et al. Ion-exchange isothermal supersaturation // Solvent Extraction and Ion Exchange. 1998. Vol. 16. No. 1. pp. 151-221.

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Muraviev D., Khamizov R., Tikhonov N. A. Ion-exchange isothermal supersaturation // Solvent Extraction and Ion Exchange. 1998. Vol. 16. No. 1. pp. 151-221.

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TY - JOUR

DO - 10.1080/07366299808934529

UR - http://www.tandfonline.com/doi/abs/10.1080/07366299808934529

TI - Ion-exchange isothermal supersaturation

T2 - Solvent Extraction and Ion Exchange

AU - Muraviev, Dmitri

AU - Khamizov, Ruslan

AU - Tikhonov, Nikolai A

PY - 1998

DA - 1998/01/01

PB - Taylor & Francis

SP - 151-221

IS - 1

VL - 16

SN - 0736-6299

SN - 1532-2262

ER -

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@article{1998_Muraviev,

author = {Dmitri Muraviev and Ruslan Khamizov and Nikolai A Tikhonov},

title = {Ion-exchange isothermal supersaturation},

journal = {Solvent Extraction and Ion Exchange},

year = {1998},

volume = {16},

publisher = {Taylor & Francis},

month = {jan},

url = {http://www.tandfonline.com/doi/abs/10.1080/07366299808934529},

number = {1},

pages = {151--221},

doi = {10.1080/07366299808934529}

}

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Muraviev, Dmitri, et al. “Ion-exchange isothermal supersaturation.” Solvent Extraction and Ion Exchange, vol. 16, no. 1, Jan. 1998, pp. 151-221. http://www.tandfonline.com/doi/abs/10.1080/07366299808934529.