,
том 340
,
издание 1
,
страницы 553-558
Trends in Structure and Growth of Higher Fullerenes Isomer Structure of C86 and C88-
Тип публикации: Journal Article
Дата публикации: 2000-03-01
SJR: —
CiteScore: —
Impact factor: —
ISSN: 1058725X
Condensed Matter Physics
Краткое описание
Abstract The isomer structure and stability of higher fullerenes is one of the most interesting issues which might be closely related with general question how a fullerene cage structure is formed. In the present study, the structures of the higher fullerenes with the sizes of C86 and C88 are described based on UV/Visible/nearIR absorption spectra and 13C NMR measurements in solution. For well-understanding the structure and growth of higher fullerenes, the isomer-free samples were prepared for all isomers associated with the C86, and C88 cages by means of a multiple stage high performance liquid chromatography (HPLC). As a result, five different isomers for C86 and C88 were successfully isolated and characterized. For these five different isomers studied in the present work, 13C NMR measurements in solution straightforwardly gave a conclusion that three of them possess the cage structures with a C2 molecular symmetry and two with a Cs molecular symmetry. The possible specific candidates for these five isomers will be discussed on the basis of both the present experimental results and recent theoretical predictions.
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MIYAKE Y. et al. Trends in Structure and Growth of Higher Fullerenes Isomer Structure of C86 and C88- // Molecular Crystals and Liquid Crystals Science and Technology Section A Molecular Crystals and Liquid Crystals. 2000. Vol. 340. No. 1. pp. 553-558.
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MIYAKE Y., Minami T., KIKUCHI K., Kainosho M., Achiba Y. Trends in Structure and Growth of Higher Fullerenes Isomer Structure of C86 and C88- // Molecular Crystals and Liquid Crystals Science and Technology Section A Molecular Crystals and Liquid Crystals. 2000. Vol. 340. No. 1. pp. 553-558.
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TY - JOUR
DO - 10.1080/10587250008025524
UR - https://www.tandfonline.com/doi/full/10.1080/10587250008025524
TI - Trends in Structure and Growth of Higher Fullerenes Isomer Structure of C86 and C88-
T2 - Molecular Crystals and Liquid Crystals Science and Technology Section A Molecular Crystals and Liquid Crystals
AU - MIYAKE, Yoko
AU - Minami, Tsuyoshi
AU - KIKUCHI, Kouichi
AU - Kainosho, Masatsune
AU - Achiba, Yohji
PY - 2000
DA - 2000/03/01
PB - Taylor & Francis
SP - 553-558
IS - 1
VL - 340
SN - 1058-725X
ER -
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@article{2000_MIYAKE,
author = {Yoko MIYAKE and Tsuyoshi Minami and Kouichi KIKUCHI and Masatsune Kainosho and Yohji Achiba},
title = {Trends in Structure and Growth of Higher Fullerenes Isomer Structure of C86 and C88-},
journal = {Molecular Crystals and Liquid Crystals Science and Technology Section A Molecular Crystals and Liquid Crystals},
year = {2000},
volume = {340},
publisher = {Taylor & Francis},
month = {mar},
url = {https://www.tandfonline.com/doi/full/10.1080/10587250008025524},
number = {1},
pages = {553--558},
doi = {10.1080/10587250008025524}
}
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MLA
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MIYAKE, Yoko, et al. “Trends in Structure and Growth of Higher Fullerenes Isomer Structure of C86 and C88-.” Molecular Crystals and Liquid Crystals Science and Technology Section A Molecular Crystals and Liquid Crystals, vol. 340, no. 1, Mar. 2000, pp. 553-558. https://www.tandfonline.com/doi/full/10.1080/10587250008025524.