Supramolecular Chemistry, volume 29, issue 5, pages 360-369
Molecular recognition of nitrogen – containing bases by Zn[5,15-bis-(2,6-dodecyloxyphenyl)]porphyrin
Maltceva Olga
1
,
Mamardashvili Galina
1
,
Khodov Ilya
1, 2
,
Khodova Veronika
3
,
Krestyaninov Michael
1
,
Mamardashvili Nugzar
1
,
Dehaen Wim
4
Publication type: Journal Article
Publication date: 2016-10-13
Journal:
Supramolecular Chemistry
Quartile SCImago
Q3
Quartile WOS
Q2
Impact factor: 3.3
ISSN: 10610278, 10290478
General Chemistry
Abstract
Abstract By means of spectrophotometric titration and 1H NMR spectroscopy, the selective binding ability of the Zn-5,15-bis-(2,6-dodecyloxyphenyl)porphyrin towards nitrogen containing organic molecules of various nature has been studied. It has been found that the presence of long alkoxy substituents at the ortho-positions of the Zn-porphyrin phenyl rings prevents the axial coordination of tertiary amines and, conversely, creates favourable conditions for binding of a primary diamine due to the presence of additional binding sites, namely the oxygen atoms of the ortho–ortho′- dodecyloxy substituents of the meso phenyl groups. The formation of stable complexes with multiple binding sites has been confirmed by DFT quantum chemical calculations and two-dimensional NMR experiments.
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1 publication, 4.35%
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1 publication, 4.35%
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1 publication, 4.35%
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1 publication, 4.35%
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1 publication, 4.35%
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1 publication, 4.35%
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1
2
3
4
5
6
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Citations by publishers
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2
4
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8
10
12
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Elsevier
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12 publications, 52.17%
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Multidisciplinary Digital Publishing Institute (MDPI)
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5 publications, 21.74%
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Springer Nature
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2 publications, 8.7%
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World Scientific
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World Scientific
1 publication, 4.35%
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Wiley
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Wiley
1 publication, 4.35%
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Ivanovo State University of Chemistry and Technology
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Ivanovo State University of Chemistry and Technology
1 publication, 4.35%
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Pleiades Publishing
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Pleiades Publishing
1 publication, 4.35%
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2
4
6
8
10
12
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Maltceva O. et al. Molecular recognition of nitrogen – containing bases by Zn[5,15-bis-(2,6-dodecyloxyphenyl)]porphyrin // Supramolecular Chemistry. 2016. Vol. 29. No. 5. pp. 360-369.
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Maltceva O., Mamardashvili G., Khodov I., Lazovskiy D., Khodova V., Krestyaninov M., Mamardashvili N., Dehaen W. Molecular recognition of nitrogen – containing bases by Zn[5,15-bis-(2,6-dodecyloxyphenyl)]porphyrin // Supramolecular Chemistry. 2016. Vol. 29. No. 5. pp. 360-369.
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TY - JOUR
DO - 10.1080/10610278.2016.1238473
UR - https://doi.org/10.1080%2F10610278.2016.1238473
TI - Molecular recognition of nitrogen – containing bases by Zn[5,15-bis-(2,6-dodecyloxyphenyl)]porphyrin
T2 - Supramolecular Chemistry
AU - Maltceva, Olga
AU - Mamardashvili, Galina
AU - Khodov, Ilya
AU - Lazovskiy, Dmitriy
AU - Khodova, Veronika
AU - Krestyaninov, Michael
AU - Mamardashvili, Nugzar
AU - Dehaen, Wim
PY - 2016
DA - 2016/10/13 00:00:00
PB - Taylor & Francis
SP - 360-369
IS - 5
VL - 29
SN - 1061-0278
SN - 1029-0478
ER -
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@article{2016_Maltceva,
author = {Olga Maltceva and Galina Mamardashvili and Ilya Khodov and Dmitriy Lazovskiy and Veronika Khodova and Michael Krestyaninov and Nugzar Mamardashvili and Wim Dehaen},
title = {Molecular recognition of nitrogen – containing bases by Zn[5,15-bis-(2,6-dodecyloxyphenyl)]porphyrin},
journal = {Supramolecular Chemistry},
year = {2016},
volume = {29},
publisher = {Taylor & Francis},
month = {oct},
url = {https://doi.org/10.1080%2F10610278.2016.1238473},
number = {5},
pages = {360--369},
doi = {10.1080/10610278.2016.1238473}
}
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Maltceva, Olga, et al. “Molecular recognition of nitrogen – containing bases by Zn[5,15-bis-(2,6-dodecyloxyphenyl)]porphyrin.” Supramolecular Chemistry, vol. 29, no. 5, Oct. 2016, pp. 360-369. https://doi.org/10.1080%2F10610278.2016.1238473.
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