CHEMICAL MECHANISMS OF CATALYTIC CRACKING OVER SOLID ACIDIC CATALYSTS: ALKANES AND ALKENES
Publication type: Journal Article
Publication date: 2001-05-31
scimago Q1
wos Q1
SJR: 2.510
CiteScore: 23.6
Impact factor: 10.1
ISSN: 01614940, 15205703
General Chemistry
Catalysis
Process Chemistry and Technology
Abstract
The review discusses chemical mechanisms of most important reactions that take place in the course of catalytic cracking of alkenes and alkanes over solid acidic catalysts. The main subject of the review is the mechanism of the principal cracking step, fission of C─C bonds in aliphatic hydrocarbons. The cracking mechanism of alkenes via carbenium ion intermediates (with complications caused by oligomerization reactions) is well established. In contrast, the C─C bond fission mechanism in alkanes is still a controversial subject. The review compares merits and difficulties of different mechanisms proposed in the literature: several carbenium-ion mechanisms, the carbonium-ion mechanism, the chain-reactions mechanism with participation of both carbonium and carbenium ions, and the oxonium-ion mechanism. Reactions accompanying C─C-bond fission in cracking reactions, hydrogen redistribution, formation of cycloalkanes, light aromatic compounds, and coke are also briefly discussed.
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Total citations:
233
Citations from 2024:
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(12.88%)
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Kissin Y. V. CHEMICAL MECHANISMS OF CATALYTIC CRACKING OVER SOLID ACIDIC CATALYSTS: ALKANES AND ALKENES // Catalysis Reviews - Science and Engineering. 2001. Vol. 43. No. 1-2. pp. 85-146.
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Kissin Y. V. CHEMICAL MECHANISMS OF CATALYTIC CRACKING OVER SOLID ACIDIC CATALYSTS: ALKANES AND ALKENES // Catalysis Reviews - Science and Engineering. 2001. Vol. 43. No. 1-2. pp. 85-146.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1081/CR-100104387
UR - https://doi.org/10.1081/CR-100104387
TI - CHEMICAL MECHANISMS OF CATALYTIC CRACKING OVER SOLID ACIDIC CATALYSTS: ALKANES AND ALKENES
T2 - Catalysis Reviews - Science and Engineering
AU - Kissin, Yury V
PY - 2001
DA - 2001/05/31
PB - Taylor & Francis
SP - 85-146
IS - 1-2
VL - 43
SN - 0161-4940
SN - 1520-5703
ER -
Cite this
BibTex (up to 50 authors)
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@article{2001_Kissin,
author = {Yury V Kissin},
title = {CHEMICAL MECHANISMS OF CATALYTIC CRACKING OVER SOLID ACIDIC CATALYSTS: ALKANES AND ALKENES},
journal = {Catalysis Reviews - Science and Engineering},
year = {2001},
volume = {43},
publisher = {Taylor & Francis},
month = {may},
url = {https://doi.org/10.1081/CR-100104387},
number = {1-2},
pages = {85--146},
doi = {10.1081/CR-100104387}
}
Cite this
MLA
Copy
Kissin, Yury V.. “CHEMICAL MECHANISMS OF CATALYTIC CRACKING OVER SOLID ACIDIC CATALYSTS: ALKANES AND ALKENES.” Catalysis Reviews - Science and Engineering, vol. 43, no. 1-2, May. 2001, pp. 85-146. https://doi.org/10.1081/CR-100104387.