Fullerenes Nanotubes and Carbon Nanostructures

, volume 11 , issue 1 , pages 61-77

Bromination of [60]Fullerene. II. Crystal and Molecular Structure of [60]Fullerene Bromides, C60Br6, C60Br8, and C60Br24

Sergei I. Troyanov ¹

Pavel A. Troshin ¹

Olga V. Boltalina ¹

E. Kemnitz ²

Hide authors affiliations Show authors affiliations: 2 affiliations

a Chemistry Department , Moscow State University , Moscow, 119899, Russia |

b Institute of Chemistry , Humboldt University of Berlin , Berlin, Germany |

Publication type: Journal Article

Publication date: 2003-03-01

Taylor & Francis

Fullerenes Nanotubes and Carbon Nanostructures

scimago Q3

wos Q3

SJR: 0.362

CiteScore: 4.0

Impact factor: 1.8

ISSN: 1536383X, 15364046

DOI: 10.1081/FST-120018665

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Organic Chemistry

Physical and Theoretical Chemistry

Atomic and Molecular Physics, and Optics

General Materials Science

Abstract

Abstract The crystal and molecular structures of the bromofullerene solvates C60Br6·0.5C6H5Cl·0.5Br2, C60Br8·1.5(o‐C6H4Cl2), C60Br8·Br2, C60Br8·0.5C6H5Br·0.5Br2, and C60Br24·2Br2 have been determined by single crystal X‐ray diffraction. The molecular species C60Br6, C60Br8, and C60Br24 which have idealized C s , C 2v , and T h symmetries, respectively, have several different types of C‒Br and C‒C bonds. A comparison between different solvates of the same bromofullerenes revealed a larger stability of the packing modes for the C60Br6 and C60Br24 solvates, whereas the C60Br8 solvates showed different packing motifs dependent on the nature and amount of the solvent molecules.

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Troyanov S. I. et al. Bromination of [60]Fullerene. II. Crystal and Molecular Structure of [60]Fullerene Bromides, C60Br6, C60Br8, and C60Br24 // Fullerenes Nanotubes and Carbon Nanostructures. 2003. Vol. 11. No. 1. pp. 61-77.

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Troyanov S. I., Troshin P. A., Boltalina O. V., Kemnitz E. Bromination of [60]Fullerene. II. Crystal and Molecular Structure of [60]Fullerene Bromides, C60Br6, C60Br8, and C60Br24 // Fullerenes Nanotubes and Carbon Nanostructures. 2003. Vol. 11. No. 1. pp. 61-77.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1081/FST-120018665

UR - https://doi.org/10.1081/FST-120018665

TI - Bromination of [60]Fullerene. II. Crystal and Molecular Structure of [60]Fullerene Bromides, C60Br6, C60Br8, and C60Br24

T2 - Fullerenes Nanotubes and Carbon Nanostructures

AU - Troyanov, Sergei I.

AU - Troshin, Pavel A.

AU - Boltalina, Olga V.

AU - Kemnitz, E.

PY - 2003

DA - 2003/03/01

PB - Taylor & Francis

SP - 61-77

IS - 1

VL - 11

SN - 1536-383X

SN - 1536-4046

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2003_Troyanov,

author = {Sergei I. Troyanov and Pavel A. Troshin and Olga V. Boltalina and E. Kemnitz},

title = {Bromination of [60]Fullerene. II. Crystal and Molecular Structure of [60]Fullerene Bromides, C60Br6, C60Br8, and C60Br24},

journal = {Fullerenes Nanotubes and Carbon Nanostructures},

year = {2003},

volume = {11},

publisher = {Taylor & Francis},

month = {mar},

url = {https://doi.org/10.1081/FST-120018665},

number = {1},

pages = {61--77},

doi = {10.1081/FST-120018665}

}

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Troyanov, Sergei I., et al. “Bromination of [60]Fullerene. II. Crystal and Molecular Structure of [60]Fullerene Bromides, C60Br6, C60Br8, and C60Br24.” Fullerenes Nanotubes and Carbon Nanostructures, vol. 11, no. 1, Mar. 2003, pp. 61-77. https://doi.org/10.1081/FST-120018665.