Fullerenes Nanotubes and Carbon Nanostructures

, том 11 , издание 2 , страницы 165-185

Some New Aspects of Chlorination of Fullerenes

Тип публикации: Journal Article

Дата публикации: 2003-06-01

Taylor & Francis

Fullerenes Nanotubes and Carbon Nanostructures

scimago Q3

wos Q3

БС2

SJR: 0.362

CiteScore: 4.0

Impact factor: 1.8

ISSN: 1536383X, 15364046

DOI: 10.1081/FST-120021142

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Organic Chemistry

Physical and Theoretical Chemistry

Atomic and Molecular Physics, and Optics

General Materials Science

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Abstract The effect of the reagent ratio, reaction time and power of the reagent on the product composition in chlorination of [60]fullerene was studied. Chlorofullerenes C60Cl6, C60Cl8, C60Cl10, C60Cl12, C60Cl14, and C60Cl26 were synthesized and characterized by chemical analysis, FTIR, 13C NMR, and MALDI TOF mass spectrometry. The experimental data supported the coexistence of several isomers of C60Cl n (n = 8, 10, 12, 14, 26); the mixtures were not separated so far. Semiempirical calculations (AM1, PM3) were used to analyze the addition patterns and resulted in the most favorable structures of C60Cl8–26. Chlorination of C70 under various conditions invariably yielded C70Cl10.

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Краевая Ольга

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Федеральный исследовательский центр проблем химической физики и медицинской химии РАН

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Бурданова Мария

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Московский физико-технический институт

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Troshin P. A., Popkov O., Lyubovskaya R. Some New Aspects of Chlorination of Fullerenes // Fullerenes Nanotubes and Carbon Nanostructures. 2003. Vol. 11. No. 2. pp. 165-185.

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Troshin P. A., Popkov O., Lyubovskaya R. Some New Aspects of Chlorination of Fullerenes // Fullerenes Nanotubes and Carbon Nanostructures. 2003. Vol. 11. No. 2. pp. 165-185.

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TY - JOUR

DO - 10.1081/FST-120021142

UR - https://doi.org/10.1081/FST-120021142

TI - Some New Aspects of Chlorination of Fullerenes

T2 - Fullerenes Nanotubes and Carbon Nanostructures

AU - Troshin, Pavel A.

AU - Popkov, O

AU - Lyubovskaya, R.N.

PY - 2003

DA - 2003/06/01

PB - Taylor & Francis

SP - 165-185

IS - 2

VL - 11

SN - 1536-383X

SN - 1536-4046

ER -

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@article{2003_Troshin,

author = {Pavel A. Troshin and O Popkov and R.N. Lyubovskaya},

title = {Some New Aspects of Chlorination of Fullerenes},

journal = {Fullerenes Nanotubes and Carbon Nanostructures},

year = {2003},

volume = {11},

publisher = {Taylor & Francis},

month = {jun},

url = {https://doi.org/10.1081/FST-120021142},

number = {2},

pages = {165--185},

doi = {10.1081/FST-120021142}

}

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Troshin, Pavel A., et al. “Some New Aspects of Chlorination of Fullerenes.” Fullerenes Nanotubes and Carbon Nanostructures, vol. 11, no. 2, Jun. 2003, pp. 165-185. https://doi.org/10.1081/FST-120021142.