Nanotechnology, volume 29, issue 11, pages 115603

Phase diagram of carbon and the factors limiting the quantity and size of natural diamonds

Publication typeJournal Article
Publication date2018-02-05
Journal: Nanotechnology
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor3.5
ISSN09574484, 13616528
General Chemistry
General Materials Science
Electrical and Electronic Engineering
Mechanical Engineering
Bioengineering
Mechanics of Materials
Abstract
Phase diagrams of carbon, and those focusing on the graphite-to-diamond transitional conditions in particular, are of great interest for fundamental and applied research. The present study introduces a number of experiments carried out to convert graphite under high-pressure conditions, showing a formation of stable phase of fullerene-type onions cross-linked by sp3-bonds in the 55-115 GPa pressure range instead of diamonds formation (even at temperature 2000-3000 K) and the already formed diamonds turn into carbon onions. Our results refute the widespread idea that diamonds can form at any pressure from 2.2 to 1000 GPa. The phase diagram built within this study allows us not only to explain the existing numerous experimental data on the formation of diamond from graphite, but also to make assumptions about the conditions of its growth in Earth's crust.

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GOST |
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GOST Copy
Perezhogin I. A. et al. Phase diagram of carbon and the factors limiting the quantity and size of natural diamonds // Nanotechnology. 2018. Vol. 29. No. 11. p. 115603.
GOST all authors (up to 50) Copy
Perezhogin I. A., Kirichenko A. N., Blank V. D., Churkin V. D., Kulnitskiy B. A., Perezhogin I., Kirichenko A. S., Denisov V. N., Erohin S. V., Sorokin P. B., Popov M. Phase diagram of carbon and the factors limiting the quantity and size of natural diamonds // Nanotechnology. 2018. Vol. 29. No. 11. p. 115603.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1088/1361-6528/aaa857
UR - https://doi.org/10.1088%2F1361-6528%2Faaa857
TI - Phase diagram of carbon and the factors limiting the quantity and size of natural diamonds
T2 - Nanotechnology
AU - Perezhogin, Igor A
AU - Popov, Mikhail
AU - Churkin, Valentin D
AU - Kirichenko, Alexey N
AU - Denisov, Viktor N
AU - Blank, Vladimir D.
AU - Kulnitskiy, Boris A.
AU - Perezhogin, Igor
AU - Kirichenko, Alexey S.
AU - Erohin, Sergey V
AU - Sorokin, Pavel B.
PY - 2018
DA - 2018/02/05 00:00:00
PB - IOP Publishing
SP - 115603
IS - 11
VL - 29
SN - 0957-4484
SN - 1361-6528
ER -
BibTex |
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BibTex Copy
@article{2018_Perezhogin,
author = {Igor A Perezhogin and Mikhail Popov and Valentin D Churkin and Alexey N Kirichenko and Viktor N Denisov and Vladimir D. Blank and Boris A. Kulnitskiy and Igor Perezhogin and Alexey S. Kirichenko and Sergey V Erohin and Pavel B. Sorokin},
title = {Phase diagram of carbon and the factors limiting the quantity and size of natural diamonds},
journal = {Nanotechnology},
year = {2018},
volume = {29},
publisher = {IOP Publishing},
month = {feb},
url = {https://doi.org/10.1088%2F1361-6528%2Faaa857},
number = {11},
pages = {115603},
doi = {10.1088/1361-6528/aaa857}
}
MLA
Cite this
MLA Copy
Perezhogin, Igor A., et al. “Phase diagram of carbon and the factors limiting the quantity and size of natural diamonds.” Nanotechnology, vol. 29, no. 11, Feb. 2018, p. 115603. https://doi.org/10.1088%2F1361-6528%2Faaa857.
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