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A stereospeifically18O-labelled deoxydinucleoside phosphate block for incorporation into an oligonucleotide
Publication type: Journal Article
Publication date: 1983-01-01
scimago Q1
wos Q1
SJR: 7.776
CiteScore: 31.7
Impact factor: 13.1
ISSN: 03051048, 13624962
PubMed ID:
6634410
Genetics
Abstract
Fully protected diastereoisomers of deoxyguanylyl (3' leads to 5') deoxyadenosine stereospecifically labelled on phosphorus with oxygen-18 have been synthesized by oxidation of phosphite triester intermediates in the presence of 18O-labelled water. The diastereoisomers have been chromatographically separated and their absolute configuration at phosphorus determined. (Rp)-[18O]deoxyguanylyl (3' leads to 5')deoxyadenosine has been prepared by complete deprotection of the parent diastereoisomer of the Sp configuration. Methylation of the former compound permits assignment of the absolute configurations of the methyl esters of N1-methyldeoxyguanylyl (3' leads to 5') N1-methyldeoxyadenosine.
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Total citations:
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Potter B. V., ECKSTEIN F., Uznanski B. A stereospeifically18O-labelled deoxydinucleoside phosphate block for incorporation into an oligonucleotide // Nucleic Acids Research. 1983. Vol. 11. No. 20. pp. 7087-7103.
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Potter B. V., ECKSTEIN F., Uznanski B. A stereospeifically18O-labelled deoxydinucleoside phosphate block for incorporation into an oligonucleotide // Nucleic Acids Research. 1983. Vol. 11. No. 20. pp. 7087-7103.
Cite this
RIS
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TY - JOUR
DO - 10.1093/nar/11.20.7087
UR - https://doi.org/10.1093/nar/11.20.7087
TI - A stereospeifically18O-labelled deoxydinucleoside phosphate block for incorporation into an oligonucleotide
T2 - Nucleic Acids Research
AU - Potter, Barry V.L.
AU - ECKSTEIN, FRITZ
AU - Uznanski, Bogdan
PY - 1983
DA - 1983/01/01
PB - Oxford University Press
SP - 7087-7103
IS - 20
VL - 11
PMID - 6634410
SN - 0305-1048
SN - 1362-4962
ER -
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BibTex (up to 50 authors)
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@article{1983_Potter,
author = {Barry V.L. Potter and FRITZ ECKSTEIN and Bogdan Uznanski},
title = {A stereospeifically18O-labelled deoxydinucleoside phosphate block for incorporation into an oligonucleotide},
journal = {Nucleic Acids Research},
year = {1983},
volume = {11},
publisher = {Oxford University Press},
month = {jan},
url = {https://doi.org/10.1093/nar/11.20.7087},
number = {20},
pages = {7087--7103},
doi = {10.1093/nar/11.20.7087}
}
Cite this
MLA
Copy
Potter, Barry V.L., et al. “A stereospeifically18O-labelled deoxydinucleoside phosphate block for incorporation into an oligonucleotide.” Nucleic Acids Research, vol. 11, no. 20, Jan. 1983, pp. 7087-7103. https://doi.org/10.1093/nar/11.20.7087.