Physical Review E, volume 107, issue 2, publication number 024503
Macroscopic forces in inhomogeneous polyelectrolyte solutions
Publication type: Journal Article
Publication date: 2023-02-15
Journal:
Physical Review E
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 2.4
ISSN: 24700045, 24700053, 15393755, 15502376, 1063651X, 10953787
Abstract
In this paper, we present a self-consistent field theory of macroscopic forces in spatially inhomogeneous flexible chain polyelectrolyte solutions. We derive an analytical expression for a stress tensor which consists of three terms: isotropic hydrostatic stress, electrostatic (Maxwell) stress, and stress rising from conformational entropy of polymer chains---conformational stress. We apply our theory to the description of polyelectrolyte solutions confined in a conductive slit nanopore and observe anomalous behavior of disjoining pressure and electric differential capacitance.
Citations by journals
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1
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Journal of Chemical Physics
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Journal of Chemical Physics
3 publications, 50%
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Soft Matter
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Soft Matter
1 publication, 16.67%
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Polymer Science - Series C
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Polymer Science - Series C
1 publication, 16.67%
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Journal of Statistical Mechanics: Theory and Experiment
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Journal of Statistical Mechanics: Theory and Experiment
1 publication, 16.67%
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1
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3
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Citations by publishers
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1
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3
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American Institute of Physics (AIP)
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American Institute of Physics (AIP)
3 publications, 50%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 16.67%
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Pleiades Publishing
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Pleiades Publishing
1 publication, 16.67%
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IOP Publishing
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IOP Publishing
1 publication, 16.67%
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1
2
3
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Budkov Y. A., Kalikin N. N. Macroscopic forces in inhomogeneous polyelectrolyte solutions // Physical Review E. 2023. Vol. 107. No. 2. 024503
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Budkov Y. A., Kalikin N. N. Macroscopic forces in inhomogeneous polyelectrolyte solutions // Physical Review E. 2023. Vol. 107. No. 2. 024503
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TY - JOUR
DO - 10.1103/physreve.107.024503
UR - https://doi.org/10.1103%2Fphysreve.107.024503
TI - Macroscopic forces in inhomogeneous polyelectrolyte solutions
T2 - Physical Review E
AU - Budkov, Yury A.
AU - Kalikin, Nikolai N.
PY - 2023
DA - 2023/02/15 00:00:00
PB - American Physical Society (APS)
IS - 2
VL - 107
SN - 2470-0045
SN - 2470-0053
SN - 1539-3755
SN - 1550-2376
SN - 1063-651X
SN - 1095-3787
ER -
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@article{2023_Budkov,
author = {Yury A. Budkov and Nikolai N. Kalikin},
title = {Macroscopic forces in inhomogeneous polyelectrolyte solutions},
journal = {Physical Review E},
year = {2023},
volume = {107},
publisher = {American Physical Society (APS)},
month = {feb},
url = {https://doi.org/10.1103%2Fphysreve.107.024503},
number = {2},
doi = {10.1103/physreve.107.024503}
}