KSm(MoO4 )2 , an incommensurately modulated and partially disordered scheelite-like structure
Alla Arakcheeva
1
,
Philip Pattison
1, 2
,
Gervais Chapuis
1
,
Marta Rossell
3
,
Andrey Filaretov
1
,
Vladimir Morozov
4
,
Gustaaf Van Tendeloo
3
Publication type: Journal Article
Publication date: 2008-03-14
SJR: —
CiteScore: —
Impact factor: —
ISSN: 01087681, 16005740
PubMed ID:
18369287
General Biochemistry, Genetics and Molecular Biology
General Medicine
Abstract
The incommensurately modulated scheelite-like KSm(MoO4)2 structure has been refined in the monoclinic superspace group I2/b(αβ0)00 by the Rietveld method on the basis of synchrotron radiation powder diffraction data. The systematic broadening of satellite reflections has been accounted for by applying anisotropic microstrain line-broadening. The microstructure has been studied by transmission electron microscopy (TEM). The partial disorder of the K and Sm cations in the A position is best approximated by a combination of harmonic and complex crenel functions with (0.952Sm + 0.048K) and (0.952K + 0.048Sm) atomic domains. This combination yields a compositional wave distribution from {KMoO4} to {SmMoO4} observed in the ab structure projection along q. The specific features of KSm(MoO4)2 and degree of the A-cation ordering are discussed in comparison with the previously reported structure of KNd(MoO4)2.
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Total citations:
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Citations from 2024:
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(3%)
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GOST
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Arakcheeva A. et al. KSm(MoO4)2, an incommensurately modulated and partially disordered scheelite-like structure // Acta Crystallographica Section B Structural Science. 2008. Vol. 64. No. 2. pp. 160-171.
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Arakcheeva A., Pattison P., Chapuis G., Rossell M., Filaretov A., Morozov V., Van Tendeloo G. KSm(MoO4)2, an incommensurately modulated and partially disordered scheelite-like structure // Acta Crystallographica Section B Structural Science. 2008. Vol. 64. No. 2. pp. 160-171.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1107/S0108768108001870
UR - https://doi.org/10.1107/S0108768108001870
TI - KSm(MoO4)2, an incommensurately modulated and partially disordered scheelite-like structure
T2 - Acta Crystallographica Section B Structural Science
AU - Arakcheeva, Alla
AU - Pattison, Philip
AU - Chapuis, Gervais
AU - Rossell, Marta
AU - Filaretov, Andrey
AU - Morozov, Vladimir
AU - Van Tendeloo, Gustaaf
PY - 2008
DA - 2008/03/14
PB - International Union of Crystallography (IUCr)
SP - 160-171
IS - 2
VL - 64
PMID - 18369287
SN - 0108-7681
SN - 1600-5740
ER -
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BibTex (up to 50 authors)
Copy
@article{2008_Arakcheeva,
author = {Alla Arakcheeva and Philip Pattison and Gervais Chapuis and Marta Rossell and Andrey Filaretov and Vladimir Morozov and Gustaaf Van Tendeloo},
title = {KSm(MoO4)2, an incommensurately modulated and partially disordered scheelite-like structure},
journal = {Acta Crystallographica Section B Structural Science},
year = {2008},
volume = {64},
publisher = {International Union of Crystallography (IUCr)},
month = {mar},
url = {https://doi.org/10.1107/S0108768108001870},
number = {2},
pages = {160--171},
doi = {10.1107/S0108768108001870}
}
Cite this
MLA
Copy
Arakcheeva, Alla, et al. “KSm(MoO4)2, an incommensurately modulated and partially disordered scheelite-like structure.” Acta Crystallographica Section B Structural Science, vol. 64, no. 2, Mar. 2008, pp. 160-171. https://doi.org/10.1107/S0108768108001870.