Structural chemistry of vanadium oxides with open frameworks
Publication type: Journal Article
Publication date: 1999-10-01
SJR: —
CiteScore: —
Impact factor: —
ISSN: 01087681, 16005740
PubMed ID:
10927405
General Biochemistry, Genetics and Molecular Biology
General Medicine
Abstract
The present work is dedicated to a crystal-chemical and topographical analysis of vanadium oxides with open structures. The review covers, apart from a few exceptions, only pure vanadium oxide structures with vanadium in oxidation states greater than +3. Purely tetrahedral frameworks are not discussed because of their traditional, well known crystal chemistry and only a few examples of cluster compounds are provided. Structural classification and notation of vanadium oxide frameworks are proposed based on the following scheme: polyhedra → chain → layer → three-dimensional framework. Thus, approximately 60 types of vanadium oxide frameworks are divided into five classes by type of coordination polyhedra present and into 14 subclasses by a more complex structural formation. Details are also given of the analysis of vanadium–oxygen coordination polyhedra and their metamorphosis: tetrahedron–trigonal bipyramid–square pyramid–octahedron, as well as the combinatorial deduction of possible structures for the most common framework types.
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319
Total citations:
319
Citations from 2025:
20
(6.27%)
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GOST
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Zavalij P. Y., Whittingham M. S. Structural chemistry of vanadium oxides with open frameworks // Acta Crystallographica Section B Structural Science. 1999. Vol. 55. No. 5. pp. 627-663.
GOST all authors (up to 50)
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Zavalij P. Y., Whittingham M. S. Structural chemistry of vanadium oxides with open frameworks // Acta Crystallographica Section B Structural Science. 1999. Vol. 55. No. 5. pp. 627-663.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1107/S0108768199004000
UR - https://doi.org/10.1107/S0108768199004000
TI - Structural chemistry of vanadium oxides with open frameworks
T2 - Acta Crystallographica Section B Structural Science
AU - Zavalij, Peter Y.
AU - Whittingham, M. Stanley
PY - 1999
DA - 1999/10/01
PB - International Union of Crystallography (IUCr)
SP - 627-663
IS - 5
VL - 55
PMID - 10927405
SN - 0108-7681
SN - 1600-5740
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1999_Zavalij,
author = {Peter Y. Zavalij and M. Stanley Whittingham},
title = {Structural chemistry of vanadium oxides with open frameworks},
journal = {Acta Crystallographica Section B Structural Science},
year = {1999},
volume = {55},
publisher = {International Union of Crystallography (IUCr)},
month = {oct},
url = {https://doi.org/10.1107/S0108768199004000},
number = {5},
pages = {627--663},
doi = {10.1107/S0108768199004000}
}
Cite this
MLA
Copy
Zavalij, Peter Y., and M. Stanley Whittingham. “Structural chemistry of vanadium oxides with open frameworks.” Acta Crystallographica Section B Structural Science, vol. 55, no. 5, Oct. 1999, pp. 627-663. https://doi.org/10.1107/S0108768199004000.