,
volume 62
,
issue 7
,
pages m303-m305
Two germatranes with bulky substituents
Eugene A. Komissarov
1
,
Nikolay P. Alekseev
2
,
Konstantin M. Pavlov
2
,
Olga V. Krivolapova
2
,
Valentin G. Lachtin
2
Publication type: Journal Article
Publication date: 2006-06-23
SJR: —
CiteScore: —
Impact factor: —
ISSN: 01082701, 16005759
PubMed ID:
16823198
General Biochemistry, Genetics and Molecular Biology
General Medicine
Abstract
In 1-adamantyl-2,8,9-trioxa-5-aza-1-germabicyclo[3.3.3]undecane or 1-adamantylgermatrane, [Ge(C10H15)(C6H12NO3)], (I), and (2,8,9-trioxa-5-aza-1-germabicyclo[3.3.3]undecan-1-yl)methyl N-cyclohexylcarbamate or [(germatran-1-yl)methyl] N-cyclohexylcarbamate, [Ge(C6H12NO3)(C8H14NO2)], (II), the Ge atoms are characterized by trigonal–bypiramidal configurations. The Ge⋯N distances [2.266 (3) and 2.206 (3) Å in (I) and (II), respectively] are among the longest observed in germatranes. The significant distortion of the apical N—Ge—C angle in (II) is caused by crystal packing effects.
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Korlyukov A. et al. Two germatranes with bulky substituents // Acta Crystallographica Section C Crystal Structure Communications. 2006. Vol. 62. No. 7. p. m303-m305.
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Korlyukov A., Komissarov E. A., Alekseev N. P., Pavlov K. M., Krivolapova O. V., Lachtin V. G. Two germatranes with bulky substituents // Acta Crystallographica Section C Crystal Structure Communications. 2006. Vol. 62. No. 7. p. m303-m305.
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RIS
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TY - JOUR
DO - 10.1107/s0108270106019317
UR - https://doi.org/10.1107/s0108270106019317
TI - Two germatranes with bulky substituents
T2 - Acta Crystallographica Section C Crystal Structure Communications
AU - Korlyukov, Alexander
AU - Komissarov, Eugene A.
AU - Alekseev, Nikolay P.
AU - Pavlov, Konstantin M.
AU - Krivolapova, Olga V.
AU - Lachtin, Valentin G.
PY - 2006
DA - 2006/06/23
PB - International Union of Crystallography (IUCr)
SP - m303-m305
IS - 7
VL - 62
PMID - 16823198
SN - 0108-2701
SN - 1600-5759
ER -
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BibTex (up to 50 authors)
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@article{2006_Korlyukov,
author = {Alexander Korlyukov and Eugene A. Komissarov and Nikolay P. Alekseev and Konstantin M. Pavlov and Olga V. Krivolapova and Valentin G. Lachtin},
title = {Two germatranes with bulky substituents},
journal = {Acta Crystallographica Section C Crystal Structure Communications},
year = {2006},
volume = {62},
publisher = {International Union of Crystallography (IUCr)},
month = {jun},
url = {https://doi.org/10.1107/s0108270106019317},
number = {7},
pages = {m303--m305},
doi = {10.1107/s0108270106019317}
}
Cite this
MLA
Copy
Korlyukov, Alexander, et al. “Two germatranes with bulky substituents.” Acta Crystallographica Section C Crystal Structure Communications, vol. 62, no. 7, Jun. 2006, pp. m303-m305. https://doi.org/10.1107/s0108270106019317.
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