Open Access
Isolation of Two Seven-Membered Ring C58 Fullerene Derivatives: C58F17CF3 and C58F18
Pavel A. Troshin
1, 2, 3
,
Anthony G. Avent
1, 2, 3
,
Adam D Darwish
1, 2, 3
,
Natalia Martsinovich
1, 2, 3
,
Ala’a K. Abdul-Sada
1, 2, 3
,
Joan M Street
1, 2, 3
,
Roger Taylor
1, 2, 3
Publication type: Journal Article
Publication date: 2005-07-08
scimago Q1
wos Q1
SJR: 10.416
CiteScore: 48.4
Impact factor: 45.8
ISSN: 00368075, 10959203
PubMed ID:
16002613
Multidisciplinary
Abstract
Fluorination of C60 at 550°C leads to milligram quantities of two stable fullerene derivatives with 58-carbon cage structures: C58F18 and C58F17CF3. The compounds were characterized by mass spectrometry and fluorine nuclear magnetic resonance spectroscopy, and the data support a heptagonal ring in the framework. The resulting strain, which has hindered past attempts to prepare these smaller quasi-fullerenes, is mitigated here by hybridization change of some of the carbons in the pentagons from sp2 to sp3 because of fluorine addition. The loss of carbon from C60 is believed to occur via sequential fluorine addition to a C–C single bond and an adjacent C[dbond]C bond, followed by loss of a :CF2 carbene.
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Metrics
150
Total citations:
150
Citations from 2024:
4
(2.66%)
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MLA
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GOST
Copy
Troshin P. A. et al. Isolation of Two Seven-Membered Ring C58 Fullerene Derivatives: C58F17CF3 and C58F18 // Science. 2005. Vol. 309. No. 5732. pp. 278-281.
GOST all authors (up to 50)
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Troshin P. A., Avent A. G., Darwish A. D., Martsinovich N., Abdul-Sada A. K., Street J. M., Taylor R. Isolation of Two Seven-Membered Ring C58 Fullerene Derivatives: C58F17CF3 and C58F18 // Science. 2005. Vol. 309. No. 5732. pp. 278-281.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1126/science.1111904
UR - https://doi.org/10.1126/science.1111904
TI - Isolation of Two Seven-Membered Ring C58 Fullerene Derivatives: C58F17CF3 and C58F18
T2 - Science
AU - Troshin, Pavel A.
AU - Avent, Anthony G.
AU - Darwish, Adam D
AU - Martsinovich, Natalia
AU - Abdul-Sada, Ala’a K.
AU - Street, Joan M
AU - Taylor, Roger
PY - 2005
DA - 2005/07/08
PB - American Association for the Advancement of Science (AAAS)
SP - 278-281
IS - 5732
VL - 309
PMID - 16002613
SN - 0036-8075
SN - 1095-9203
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2005_Troshin,
author = {Pavel A. Troshin and Anthony G. Avent and Adam D Darwish and Natalia Martsinovich and Ala’a K. Abdul-Sada and Joan M Street and Roger Taylor},
title = {Isolation of Two Seven-Membered Ring C58 Fullerene Derivatives: C58F17CF3 and C58F18},
journal = {Science},
year = {2005},
volume = {309},
publisher = {American Association for the Advancement of Science (AAAS)},
month = {jul},
url = {https://doi.org/10.1126/science.1111904},
number = {5732},
pages = {278--281},
doi = {10.1126/science.1111904}
}
Cite this
MLA
Copy
Troshin, Pavel A., et al. “Isolation of Two Seven-Membered Ring C58 Fullerene Derivatives: C58F17CF3 and C58F18.” Science, vol. 309, no. 5732, Jul. 2005, pp. 278-281. https://doi.org/10.1126/science.1111904.
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