Open Access
Science, volume 355, issue 6323, pages 374-376
Synthesis and characterization of the pentazolate anion cyclo -N 5 ˉ in (N 5 ) 6 (H 3 O) 3 (NH 4 ) 4 Cl
Publication type: Journal Article
Publication date: 2017-01-27
Journal:
Science
Quartile SCImago
Q1
Quartile WOS
Q1
SJR: 11.902
CiteScore: 61.1
Impact factor: 44.7
ISSN: 00368075, 10959203
Multidisciplinary
Abstract
A salty route to an all-nitrogen ring
The flip side of the robust stability of N 2 is the instability of any larger molecules composed exclusively of nitrogen. These molecules nonetheless remain enticing targets for explosive and propellant applications. Zhang et al. successfully prepared the pentazolate ion, a negatively charged ring of five nitrogens, by oxidative cleavage of a C–N bond in an aryl-substituted precursor (see the Perspective by Christe). The molecule was stabilized and isolated in the solid state as a hydrated ammonium chloride salt. Spectroscopic and crystallographic characterization confirmed the ring's planar geometry.
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Zhang C. et al. Synthesis and characterization of the pentazolate anion cyclo -N 5 ˉ in (N 5 ) 6 (H 3 O) 3 (NH 4 ) 4 Cl // Science. 2017. Vol. 355. No. 6323. pp. 374-376.
GOST all authors (up to 50)
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Zhang C., Sun C., Hu B., Yu C., Lu M. Synthesis and characterization of the pentazolate anion cyclo -N 5 ˉ in (N 5 ) 6 (H 3 O) 3 (NH 4 ) 4 Cl // Science. 2017. Vol. 355. No. 6323. pp. 374-376.
Cite this
RIS
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TY - JOUR
DO - 10.1126/science.aah3840
UR - https://doi.org/10.1126/science.aah3840
TI - Synthesis and characterization of the pentazolate anion cyclo -N 5 ˉ in (N 5 ) 6 (H 3 O) 3 (NH 4 ) 4 Cl
T2 - Science
AU - Zhang, Chong
AU - Sun, Chengguo
AU - Hu, Bingcheng
AU - Yu, Chuanming
AU - Lu, Ming
PY - 2017
DA - 2017/01/27
PB - American Association for the Advancement of Science (AAAS)
SP - 374-376
IS - 6323
VL - 355
SN - 0036-8075
SN - 1095-9203
ER -
Cite this
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@article{2017_Zhang,
author = {Chong Zhang and Chengguo Sun and Bingcheng Hu and Chuanming Yu and Ming Lu},
title = {Synthesis and characterization of the pentazolate anion cyclo -N 5 ˉ in (N 5 ) 6 (H 3 O) 3 (NH 4 ) 4 Cl},
journal = {Science},
year = {2017},
volume = {355},
publisher = {American Association for the Advancement of Science (AAAS)},
month = {jan},
url = {https://doi.org/10.1126/science.aah3840},
number = {6323},
pages = {374--376},
doi = {10.1126/science.aah3840}
}
Cite this
MLA
Copy
Zhang, Chong, et al. “Synthesis and characterization of the pentazolate anion cyclo -N 5 ˉ in (N 5 ) 6 (H 3 O) 3 (NH 4 ) 4 Cl.” Science, vol. 355, no. 6323, Jan. 2017, pp. 374-376. https://doi.org/10.1126/science.aah3840.