Open Access
The Promotional Effect of Gold in Catalysis by Palladium-Gold
Тип публикации: Journal Article
Дата публикации: 2005-10-14
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 10.948
CiteScore: 44.6
Impact factor: 47.3
ISSN: 00368075, 10959203
PubMed ID:
16224016
Multidisciplinary
Краткое описание
Acetoxylation of ethylene to vinyl acetate (VA) was used to investigate the mechanism of the promotional effect of gold (Au) in a palladium (Pd)-Au alloy catalyst. The enhanced rates of VA formation for low Pd coverages relative to high Pd coverages on Au single-crystal surfaces demonstrate that the critical reaction site for VA synthesis consists of two noncontiguous, suitably spaced, Pd monomers. The role of Au is to isolate single Pd sites that facilitate the coupling of critical surface species to product, while inhibiting the formation of undesirable reaction by-products.
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ГОСТ
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Chen M. et al. The Promotional Effect of Gold in Catalysis by Palladium-Gold // Science. 2005. Vol. 310. No. 5746. pp. 291-293.
ГОСТ со всеми авторами (до 50)
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Chen M., Kumar D., Yi C., Goodman D. The Promotional Effect of Gold in Catalysis by Palladium-Gold // Science. 2005. Vol. 310. No. 5746. pp. 291-293.
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RIS
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TY - JOUR
DO - 10.1126/science.1115800
UR - https://doi.org/10.1126/science.1115800
TI - The Promotional Effect of Gold in Catalysis by Palladium-Gold
T2 - Science
AU - Chen, Mingshu
AU - Kumar, Dheeraj
AU - Yi, Cheol-Woo
AU - Goodman, D.Wayne
PY - 2005
DA - 2005/10/14
PB - American Association for the Advancement of Science (AAAS)
SP - 291-293
IS - 5746
VL - 310
PMID - 16224016
SN - 0036-8075
SN - 1095-9203
ER -
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BibTex (до 50 авторов)
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@article{2005_Chen,
author = {Mingshu Chen and Dheeraj Kumar and Cheol-Woo Yi and D.Wayne Goodman},
title = {The Promotional Effect of Gold in Catalysis by Palladium-Gold},
journal = {Science},
year = {2005},
volume = {310},
publisher = {American Association for the Advancement of Science (AAAS)},
month = {oct},
url = {https://doi.org/10.1126/science.1115800},
number = {5746},
pages = {291--293},
doi = {10.1126/science.1115800}
}
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MLA
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Chen, Mingshu, et al. “The Promotional Effect of Gold in Catalysis by Palladium-Gold.” Science, vol. 310, no. 5746, Oct. 2005, pp. 291-293. https://doi.org/10.1126/science.1115800.
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