Open Access
Organic semiconductor photocatalyst can bifunctionalize arenes and heteroarenes
Publication type: Journal Article
Publication date: 2019-07-26
scimago Q1
wos Q1
SJR: 10.416
CiteScore: 48.4
Impact factor: 45.8
ISSN: 00368075, 10959203
PubMed ID:
31346061
Multidisciplinary
Abstract
Two-for-one approach to photoredox
In photoredox catalysis, an excited chromophore typically activates a single reactant either by oxidizing or reducing it. Ghosh et al. used a semiconductor catalyst to activate two reactants at once by quenching both an excited electron and the residual positive hole (see the Perspective by Swift). As such, two different reactive carbon or halide fragments could be appended to separate sites on an aryl ring. The catalyst also tolerated strong nucleophiles such as cyanide and could be recovered easily and reused.
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Metrics
525
Total citations:
525
Citations from 2024:
140
(26%)
Cite this
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MLA
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GOST
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Ghosh I. R. et al. Organic semiconductor photocatalyst can bifunctionalize arenes and heteroarenes // Science. 2019. Vol. 365. No. 6451. pp. 360-366.
GOST all authors (up to 50)
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Ghosh I. R., Khamrai J., Savateev O., Shlapakov N. S., Antonietti M., König B. Organic semiconductor photocatalyst can bifunctionalize arenes and heteroarenes // Science. 2019. Vol. 365. No. 6451. pp. 360-366.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1126/science.aaw3254
UR - https://doi.org/10.1126/science.aaw3254
TI - Organic semiconductor photocatalyst can bifunctionalize arenes and heteroarenes
T2 - Science
AU - Ghosh, Indrajit R.
AU - Khamrai, Jagadish
AU - Savateev, Oleksandr
AU - Shlapakov, Nikita S
AU - Antonietti, Markus
AU - König, Burkhard
PY - 2019
DA - 2019/07/26
PB - American Association for the Advancement of Science (AAAS)
SP - 360-366
IS - 6451
VL - 365
PMID - 31346061
SN - 0036-8075
SN - 1095-9203
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Ghosh,
author = {Indrajit R. Ghosh and Jagadish Khamrai and Oleksandr Savateev and Nikita S Shlapakov and Markus Antonietti and Burkhard König},
title = {Organic semiconductor photocatalyst can bifunctionalize arenes and heteroarenes},
journal = {Science},
year = {2019},
volume = {365},
publisher = {American Association for the Advancement of Science (AAAS)},
month = {jul},
url = {https://doi.org/10.1126/science.aaw3254},
number = {6451},
pages = {360--366},
doi = {10.1126/science.aaw3254}
}
Cite this
MLA
Copy
Ghosh, Indrajit R., et al. “Organic semiconductor photocatalyst can bifunctionalize arenes and heteroarenes.” Science, vol. 365, no. 6451, Jul. 2019, pp. 360-366. https://doi.org/10.1126/science.aaw3254.