Open Access
Hydrodealkenylative C(sp 3 )–C(sp 2 ) bond fragmentation
Тип публикации: Journal Article
Дата публикации: 2019-05-17
scimago Q1
wos Q1
БС1
SJR: 10.416
CiteScore: 48.4
Impact factor: 45.8
ISSN: 00368075, 10959203
PubMed ID:
31097667
Multidisciplinary
Краткое описание
Excising an olefin
Plants produce an abundance of structurally complex terpene compounds that are useful precursors to pharmaceuticals and other fine chemicals. However, the carbon frameworks of these compounds constrain the available pathways for diversification. Smaligo et al. now show that successive treatment with ozone, an iron oxidant, and a hydrogen-atom donor can cleanly cleave pendant olefins from terpenes and related compounds (see the Perspective by Caille). Breaking the bond between saturated and double-bonded carbon centers offers a direct route to desirable chiral intermediates from readily available, inexpensive precursors.
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MLA
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ГОСТ
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Smaligo A. J. et al. Hydrodealkenylative C(sp 3 )–C(sp 2 ) bond fragmentation // Science. 2019. Vol. 364. No. 6441. pp. 681-685.
ГОСТ со всеми авторами (до 50)
Скопировать
Smaligo A. J., Swain M., Quintana J. C., Tan M. F., Kim D. A., Kwon O. Hydrodealkenylative C(sp 3 )–C(sp 2 ) bond fragmentation // Science. 2019. Vol. 364. No. 6441. pp. 681-685.
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RIS
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TY - JOUR
DO - 10.1126/science.aaw4212
UR - https://doi.org/10.1126/science.aaw4212
TI - Hydrodealkenylative C(sp 3 )–C(sp 2 ) bond fragmentation
T2 - Science
AU - Smaligo, Andrew J
AU - Swain, Manisha
AU - Quintana, Jason C
AU - Tan, Mikayla F
AU - Kim, Danielle A
AU - Kwon, Ohyun
PY - 2019
DA - 2019/05/17
PB - American Association for the Advancement of Science (AAAS)
SP - 681-685
IS - 6441
VL - 364
PMID - 31097667
SN - 0036-8075
SN - 1095-9203
ER -
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BibTex (до 50 авторов)
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@article{2019_Smaligo,
author = {Andrew J Smaligo and Manisha Swain and Jason C Quintana and Mikayla F Tan and Danielle A Kim and Ohyun Kwon},
title = {Hydrodealkenylative C(sp 3 )–C(sp 2 ) bond fragmentation},
journal = {Science},
year = {2019},
volume = {364},
publisher = {American Association for the Advancement of Science (AAAS)},
month = {may},
url = {https://doi.org/10.1126/science.aaw4212},
number = {6441},
pages = {681--685},
doi = {10.1126/science.aaw4212}
}
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MLA
Скопировать
Smaligo, Andrew J., et al. “Hydrodealkenylative C(sp 3 )–C(sp 2 ) bond fragmentation.” Science, vol. 364, no. 6441, May. 2019, pp. 681-685. https://doi.org/10.1126/science.aaw4212.