Open Access
A precise polyrotaxane synthesizer
Yunyan Qiu
1
,
Bo Song
1, 2
,
Cristian Pezzato
1
,
Dengke Shen
1
,
Wenqi Liu
1
,
Long Zhang
1
,
Yuanning Feng
1
,
Qing-Hui Guo
1
,
Kang Cai
1
,
Weixingyue Li
1
,
Hongliang Chen
1
,
Minh T Nguyen
1
,
Yi Shi
1
,
C L Cheng
1
,
R.D. Astumian
3
,
Xiaopeng Li
2
,
J Fraser Stoddart
1, 4, 5
Publication type: Journal Article
Publication date: 2020-06-12
scimago Q1
wos Q1
SJR: 10.416
CiteScore: 48.4
Impact factor: 45.8
ISSN: 00368075, 10959203
PubMed ID:
32527831
Multidisciplinary
Abstract
Ten rings on one axle
Rotaxanes consist of molecular rings threaded on a central axle. Most approaches to their synthesis have focused on introducing a single ring per axle. Qiu et al. now report a systematic approach to threading up to 10 adjacent rings consecutively. The axle's end groups were constructed to attract free-floating rings when reduced and then to push those rings toward the center upon oxidation. Products of each successive reduction-oxidation cycle were characterized by nuclear magnetic resonance spectroscopy and mass spectrometry.
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Metrics
208
Total citations:
208
Citations from 2024:
72
(34%)
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MLA
Cite this
GOST
Copy
Qiu Y. et al. A precise polyrotaxane synthesizer // Science. 2020. Vol. 368. No. 6496. pp. 1247-1253.
GOST all authors (up to 50)
Copy
Qiu Y., Song B., Pezzato C., Shen D., Liu W., Zhang L., Feng Y., Guo Q., Cai K., Li W., Chen H., Nguyen M. T., Shi Y., Cheng C. L., Astumian R., Li X., Stoddart J. F. A precise polyrotaxane synthesizer // Science. 2020. Vol. 368. No. 6496. pp. 1247-1253.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1126/science.abb3962
UR - https://doi.org/10.1126/science.abb3962
TI - A precise polyrotaxane synthesizer
T2 - Science
AU - Qiu, Yunyan
AU - Song, Bo
AU - Pezzato, Cristian
AU - Shen, Dengke
AU - Liu, Wenqi
AU - Zhang, Long
AU - Feng, Yuanning
AU - Guo, Qing-Hui
AU - Cai, Kang
AU - Li, Weixingyue
AU - Chen, Hongliang
AU - Nguyen, Minh T
AU - Shi, Yi
AU - Cheng, C L
AU - Astumian, R.D.
AU - Li, Xiaopeng
AU - Stoddart, J Fraser
PY - 2020
DA - 2020/06/12
PB - American Association for the Advancement of Science (AAAS)
SP - 1247-1253
IS - 6496
VL - 368
PMID - 32527831
SN - 0036-8075
SN - 1095-9203
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2020_Qiu,
author = {Yunyan Qiu and Bo Song and Cristian Pezzato and Dengke Shen and Wenqi Liu and Long Zhang and Yuanning Feng and Qing-Hui Guo and Kang Cai and Weixingyue Li and Hongliang Chen and Minh T Nguyen and Yi Shi and C L Cheng and R.D. Astumian and Xiaopeng Li and J Fraser Stoddart},
title = {A precise polyrotaxane synthesizer},
journal = {Science},
year = {2020},
volume = {368},
publisher = {American Association for the Advancement of Science (AAAS)},
month = {jun},
url = {https://doi.org/10.1126/science.abb3962},
number = {6496},
pages = {1247--1253},
doi = {10.1126/science.abb3962}
}
Cite this
MLA
Copy
Qiu, Yunyan, et al. “A precise polyrotaxane synthesizer.” Science, vol. 368, no. 6496, Jun. 2020, pp. 1247-1253. https://doi.org/10.1126/science.abb3962.