Colloid Journal

, volume 78 , issue 5 , pages 608-615

Sol–gel transition and rheological properties of silica nanoparticle dispersions

S O Ilyin ¹

M P Arinina ¹

A Ya Malkin ¹

V. G. Kulichikhin ^{1, 2}

Hide authors affiliations Show authors affiliations: 2 affiliations

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia |

Faculty of Fundamental Physical and Chemical Engineering, Moscow State University, Moscow, Russia |

Publication type: Journal Article

Publication date: 2016-09-26

Pleiades Publishing

Colloid Journal

scimago Q4

wos Q4

SJR: 0.220

CiteScore: 2.3

Impact factor: 1.1

ISSN: 1061933X, 16083067

DOI: 10.1134/S1061933X16050070

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Physical and Theoretical Chemistry

Colloid and Surface Chemistry

Surfaces and Interfaces

Abstract

Possible variants of the rheological behavior of silica model dispersions have been analyzed. Different types of interaction between the particles and a dispersion medium make it possible to obtain different systems from low-viscosity sols to gels. Proton-donor (water) and aprotic (dimethyl sulfoxide) media have been used for comparison. Dispersions in the aprotic medium behave as non-Newtonian viscous fluids exhibiting shear thinning or shear thickening depending on deformation rate. Aqueous dispersions are viscoelastic and viscoplastic objects that exhibit the shear thickening at stresses higher than the yield stress. The introduction of small amounts of poly(ethylene oxide) into the organic dispersion medium initiates gelation. An increase in the polymer content in the dispersion medium above the concentration corresponding to the formation of a macromolecular network promotes an increase in stiffness and strength of the gels. The rheological behavior of gels is influenced by the polymer molecular mass and its affinity for a solvent.

Found

34 citations

Ilyin Sergey

PhD in Chemistry

144 publications, 3 014 citations, 623 reviews

h-index: 34

A.V. Topchiev Institute of Petrochemical Synthesis RAS

High molecular weight compounds

Rheology

2 citations

Ilyina Svetlana

6 publications, 21 citations

h-index: 3

A.V. Topchiev Institute of Petrochemical Synthesis RAS

Mendeleev University of Chemical Technology of Russia

Research interests

Mechanics and rheology of polymers

Phase-shifting materials

Polymer composite materials

Rheology

1 citation

Daudi Dauddin

🥼 🤝

PhD in Economics

6 publications, 4 citations

Economics (theory of innovation processes)

1 citation

Vinokurov Vladimir

🤝

DSc in Chemistry, professor

304 publications, 5 153 citations, 5 reviews

h-index: 39

National University of Oil and Gas «Gubkin University»

Research interests

Biotechnology

1 citation

Morozova Sofia

🥼

PhD in Chemistry

46 publications, 1 079 citations, 131 reviews

h-index: 17

Moscow Institute of Physics and Technology

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GOST |

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GOST Copy

Ilyin S. O. et al. Sol–gel transition and rheological properties of silica nanoparticle dispersions // Colloid Journal. 2016. Vol. 78. No. 5. pp. 608-615.

GOST all authors (up to 50) Copy

Ilyin S. O., Arinina M. P., Malkin A. Ya., Kulichikhin V. G. Sol–gel transition and rheological properties of silica nanoparticle dispersions // Colloid Journal. 2016. Vol. 78. No. 5. pp. 608-615.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1134/S1061933X16050070

UR - https://doi.org/10.1134/S1061933X16050070

TI - Sol–gel transition and rheological properties of silica nanoparticle dispersions

T2 - Colloid Journal

AU - Ilyin, S O

AU - Arinina, M P

AU - Malkin, A Ya

AU - Kulichikhin, V. G.

PY - 2016

DA - 2016/09/26

PB - Pleiades Publishing

SP - 608-615

IS - 5

VL - 78

SN - 1061-933X

SN - 1608-3067

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2016_Ilyin,

author = {S O Ilyin and M P Arinina and A Ya Malkin and V. G. Kulichikhin},

title = {Sol–gel transition and rheological properties of silica nanoparticle dispersions},

journal = {Colloid Journal},

year = {2016},

volume = {78},

publisher = {Pleiades Publishing},

month = {sep},

url = {https://doi.org/10.1134/S1061933X16050070},

number = {5},

pages = {608--615},

doi = {10.1134/S1061933X16050070}

}

MLA

Cite this

MLA Copy

Ilyin, S. O., et al. “Sol–gel transition and rheological properties of silica nanoparticle dispersions.” Colloid Journal, vol. 78, no. 5, Sep. 2016, pp. 608-615. https://doi.org/10.1134/S1061933X16050070.

Publisher

Pleiades Publishing

Journal

Colloid Journal

scimago Q4

wos Q4

SJR

0.220

CiteScore

2.3

Impact factor

1.1

ISSN

1061933X (Print)

16083067 (Electronic)

Profiles

Sergey Olegovich Ilyin