Hypercrosslinked polystyrene: The first nanoporous polymeric material
Publication type: Journal Article
Publication date: 2009-10-19
SJR: —
CiteScore: —
Impact factor: —
ISSN: 19950780, 19950799
Condensed Matter Physics
General Materials Science
General Engineering
Abstract
The principles of synthesis—the structural and distinctive features of hypercrosslinked polystyrene—are described. The material is obtained by intensely crosslinking the solvated polystyrene chains with rigid bridging spacers. The resulting single-phase open-worked elastic network can be considerably deformed upon swelling or the application of an external force. The huge free volume in the rigid hypercrosslinked network, which is essentially a porosity of a new type, is formed by interchain nanosized cavities (1.5–3 nm). The complete availability of the interior structure of hypercrosslinked polystyrene for low-molecular-weight compounds and the considerable uncompensated force field of polymer chains separated by spacers determines the excellent adsorption properties of the material. Several processes that are possible only due to the use of nanoporous hypercrosslinked polystyrene as a sorbent for chromatography or a matrix for preparing nanocomposites are briefly described in the paper.
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Metrics
49
Total citations:
49
Citations from 2025:
3
(6.25%)
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GOST
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Tsyurupa M. P. et al. Hypercrosslinked polystyrene: The first nanoporous polymeric material // Nanotechnologies in Russia. 2009. Vol. 4. No. 9-10. pp. 665-675.
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Tsyurupa M. P., Blinnikova Z. K., Proskurina N. A., Pastukhov A. V., Pavlova L. A., Davankov V. A. Hypercrosslinked polystyrene: The first nanoporous polymeric material // Nanotechnologies in Russia. 2009. Vol. 4. No. 9-10. pp. 665-675.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S1995078009090109
UR - https://doi.org/10.1134/S1995078009090109
TI - Hypercrosslinked polystyrene: The first nanoporous polymeric material
T2 - Nanotechnologies in Russia
AU - Tsyurupa, M. P.
AU - Blinnikova, Z. K.
AU - Proskurina, N A
AU - Pastukhov, A V
AU - Pavlova, L. A.
AU - Davankov, V. A.
PY - 2009
DA - 2009/10/19
PB - Pleiades Publishing
SP - 665-675
IS - 9-10
VL - 4
SN - 1995-0780
SN - 1995-0799
ER -
Cite this
BibTex (up to 50 authors)
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@article{2009_Tsyurupa,
author = {M. P. Tsyurupa and Z. K. Blinnikova and N A Proskurina and A V Pastukhov and L. A. Pavlova and V. A. Davankov},
title = {Hypercrosslinked polystyrene: The first nanoporous polymeric material},
journal = {Nanotechnologies in Russia},
year = {2009},
volume = {4},
publisher = {Pleiades Publishing},
month = {oct},
url = {https://doi.org/10.1134/S1995078009090109},
number = {9-10},
pages = {665--675},
doi = {10.1134/S1995078009090109}
}
Cite this
MLA
Copy
Tsyurupa, M. P., et al. “Hypercrosslinked polystyrene: The first nanoporous polymeric material.” Nanotechnologies in Russia, vol. 4, no. 9-10, Oct. 2009, pp. 665-675. https://doi.org/10.1134/S1995078009090109.