Metathesis Polymerization of 5-n-Butyl-2-Norbornene in the Presence of Dimethyl Maleate
Publication type: Journal Article
Publication date: 2023-12-01
scimago Q3
wos Q4
SJR: 0.234
CiteScore: 1.8
Impact factor: 1.0
ISSN: 15600904, 15556123
Materials Chemistry
Ceramics and Composites
Polymers and Plastics
Abstract
The interaction of the second-generation Grubbs catalyst and dimethyl maleate is investigated. It is shown that this interaction affords a new ruthenium-carbene complex capable of participating in the metathesis reaction. The metathesis homopolymerization of cyclooctene and 5-n-butyl-2-norbornene mediated by the first- or second-generation Grubbs catalyst in the presence of dimethyl maleate acting as a chain transfer agent is studied in detail. Conditions for the synthesis of previously unknown telechelic poly(5-n-butyl-2-norbornene) are optimized. The formation of heterodyads between the polyene block and dimethyl maleate fragments is revealed. Effect of the concentration of initial reactants, their ratio, accessibility of the main-chain double bond of polyene, catalyst type, temperature, and reaction time on the molecular weight and depth of the cross-metathesis reaction is explored. The efficiency of using dimethyl maleate as a chain transfer agent is demonstrated.
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Stepanyants V. R. et al. Metathesis Polymerization of 5-n-Butyl-2-Norbornene in the Presence of Dimethyl Maleate // Polymer Science - Series B. 2023. Vol. 65. No. 6. pp. 760-772.
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Stepanyants V. R., Nazemutdinova V. R., Zhigarev V. A., Sadovnikov K. S., Wozniak A. I., Morontsev A. A., Bermeshev M. V. Metathesis Polymerization of 5-n-Butyl-2-Norbornene in the Presence of Dimethyl Maleate // Polymer Science - Series B. 2023. Vol. 65. No. 6. pp. 760-772.
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TY - JOUR
DO - 10.1134/s1560090423600249
UR - https://link.springer.com/10.1134/S1560090423600249
TI - Metathesis Polymerization of 5-n-Butyl-2-Norbornene in the Presence of Dimethyl Maleate
T2 - Polymer Science - Series B
AU - Stepanyants, V. R.
AU - Nazemutdinova, V. R.
AU - Zhigarev, V A
AU - Sadovnikov, K. S.
AU - Wozniak, A I
AU - Morontsev, A A
AU - Bermeshev, M. V.
PY - 2023
DA - 2023/12/01
PB - Pleiades Publishing
SP - 760-772
IS - 6
VL - 65
SN - 1560-0904
SN - 1555-6123
ER -
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@article{2023_Stepanyants,
author = {V. R. Stepanyants and V. R. Nazemutdinova and V A Zhigarev and K. S. Sadovnikov and A I Wozniak and A A Morontsev and M. V. Bermeshev},
title = {Metathesis Polymerization of 5-n-Butyl-2-Norbornene in the Presence of Dimethyl Maleate},
journal = {Polymer Science - Series B},
year = {2023},
volume = {65},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://link.springer.com/10.1134/S1560090423600249},
number = {6},
pages = {760--772},
doi = {10.1134/s1560090423600249}
}
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Stepanyants, V. R., et al. “Metathesis Polymerization of 5-n-Butyl-2-Norbornene in the Presence of Dimethyl Maleate.” Polymer Science - Series B, vol. 65, no. 6, Dec. 2023, pp. 760-772. https://link.springer.com/10.1134/S1560090423600249.